含氮修饰的纳米稀土氧化物的摩擦学性能研究分析化学专业论文.docxVIP

摘要 摘要 II II 中时添加剂才能更好的发挥其抗磨性能，添加剂纳米 La2O3 以及邻苯二胺表面修饰纳米 CeO2 在一定条件下不同程度的增大了 3#通用锂基脂的摩擦系数。 关键词：纳米稀土氧化物，表面修饰，润滑油添加剂，抗磨性能 Abst Abstract TRIBOLOGY STUDY OF SURFACE MODIFIED NANO-RARE EARTH OXIDES ABSTRACT With the constant updating of the machinery, equipment and performance, and the increasingly demanding environmental requirements, the low-sulfur and phosphate-free and efficient multi-purpose lubricant additives were needed by multiple lubrication systems. In the same time, the fuel oils were developing to low-sulfur and low-olefin direction, the catalytic converters were required to install by gasoline vehicles, and the diesel cars should increase the exhaust gas recirculation system, so it requires the lubricants with low sulfur and low phosphorus. So, it has very important significance to study of the low-sulfur, low-phosphorus, even phosphorus-free, lubricant oil additives. The rare earth compound has excellent chemical stability and excellent lubricating properties, and the special structure of the 4f electron shell of the rare earth relate to its lubrication. For the high diffusivity, large surface area, low melting, easy sintering properties hardness and other characteristics of the nano-materials, so it is easy to form a layer of easy shearing lubricating film on the friction surface to reduce the coefficient of fiction, while it can fill and repair the worn surfaces. Between the fiction surfaces, the approximately spherical nanoparticles play the role of micro-bearings, so it can make the fiction surfaces polished and strengthening and supporting the load, increasing carrying capacity, and reducing the fiction coefficient at the same time. The analysis shows that the excellent abrasion resistance and outstanding resistance to extreme pressure properties of the nano additives make it suitable for low-speed, heavy-duty, high-temperature environment. Different from the general solid lubricating materials, the nanoparticles have the advantages both of the solid an