溶胶凝胶法制备纳米TiO2及其光催化活性的研究-河北科技大学学报.PDF

28 3 Vol. 28, No . 3 2007 9 Journal of Hebei University of Science and T ec nology Sept. 2007 : 2007) T iO2 王彦红, 王德松, 李雪艳, 罗青枝, 岳建霞 ( 河北科技大学理学院, 河北石家庄 050018) : 采用溶胶凝胶法制备纳米二氧化钛, 以甲基橙为模 污染物, 考察了影响纳米二氧化钛光 催化活性的主要因素, 并采用T EM, XRD 等方法对样品进行了表征结果表明: 具有较高光催化 活性的纳米二氧化钛的制备条件是钛酸 丁酯无水乙醇冰乙酸水的比例(体积比) 为101984, 500 下煅烧2 ; 纳米二氧化钛质量浓度为1 g/ L 时光催化效果最佳; 纳米TiO2 具有锐钛矿 晶 体结构, 平均粒径为10~ 20 nm : 溶胶凝胶法; 纳米二氧化钛; 甲基橙; 光催化活性 : O649. 4 : A Study on p otocatalytic activity of nanoT iO2 prepared by solgel met od WANG Yan ong, WANG Desong, LI Xueyan, LU O Qingz i, YU E Jianxia ( College of Sciences, Hebei University of Science and T ec nology, S ijiaz uang Hebei 050018, C ina) Abstract: NanoT iO particles w as prepared by solgel met od. A lot of factors t at affect t e p otocatalytic activity of nano 2 TiO w ere studied by t e degradation of met yl orange. T e obtained TiO are c aracterized by T EM, XRD, etc. Results s ow 2 2 t at TiO s ow s optimal p otocatalytic activit y w en t e volume ratio of TNB, et anol, acet ic acid and distilled w ater is 2 10 1984, baked at 500 for 2 ours, and t e proper dosage of TiO is 1 g/ L; t e asprepared T iO is anatase p ase, and 2 2 t e mean size is 10~ 20 nm. Key words: solgel met od; nanoTiO ; met yl orange; p otocatalytic activity 2 , , , , , , N , T iO2 , ZnO, CdS, SnO2 , WO3 , Fe2 O3 TiO2 , [ 1~ 6] , , [ 7] T iO2 , TiO2 1 : : :