磁黄铁矿与乙黄药相互作用电化学浮选红外光谱的研究-矿冶工程.PDF

24 5 矿　冶　工　程 Vo .24 №5 2004 10 MININGAN METALLURGICAL ENGINEERING O ctober 2004 ① 张　芹, 胡岳华, 顾帼华, 徐　竟 ( , 410083) 　:, pH=1 ～12 , , pH 12 , 。, , pH , , -pH 。, , pH , , 。 :;;; :TD923 :A :0253-6099(2004)05-0042-03 The Study on the Interaction between Ethyl Xanthate and Pyrrhotite in Electrochemical Flotation by FTIR Spectroscopy ZHANG Qin, HU Yue-hua, GU Guo-hua, XU Jing (S chool of Resources Processing B i-engineering , Central South University , Changsha 410083, China ) Abstract:The f otation behavior of pyrrhotite was investigated by using ethy xanthate as a co ector .The resu ts showed that pyrrhotite had good f oatabi ity when pH=1 ～11, and poor f oatabi ity when pH12.The e ectrica potentia of pu p was ad- justed by using ammonium persu fate [(NH )S O ] and sodium thiosu fate (Na S O ).The re ationship between f oatabi ity 4 2 2 8 2 2 4 and e ectrica potentia pu p for pyrrhotite in different pH va ue has been investigated, obtaining potentia -pH range for f oat- ab e pyrrhotite .The mechanism of action for ethy xanthate and production on the surface of pyrrhotite has been investigated by FTIR spectroscopy, and it is found when pyrrhotite acting with ethy xanthate in the different pH va ue and at the different e ectric potentia , the infrared absorption and recovery of pyrrhotite has a corresponding re ationship.The main adsorption product on pyrrhotite is dixanthogen. Key words:ethy xanthat;pyrrhotite;e ectrochemica f otation ;FTIR spectroscopy 　　(Fe1-x S, 0x0.223 ) 、 [6 ～8] [9] ,。 。Cheng pH ()x