含肽键（-CONH）芳酰腙、1，10-菲啰啉与稀土配合物的研究-化学(物理化学)专业论文.docxVIP

摘要程水黪混合漆裁审，弑2*羰瑟灏黢楚(耪酸艨(c{oHloN204，璃硒及l，lO-藜嗲旗 摘要 程水黪混合漆裁审，弑2*羰瑟灏黢楚(耪酸艨(c{oHloN204，璃硒及l，lO-藜嗲旗 (C,2HsN2，phen)萼褥主雕一如、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Er、Yb、Lu 秘的敬硝羧薤爱盛，合成了{2辩泰藏文歙李嚣遴戆瓣合携，经嚣索分凝、tR、专Ⅳ、 粥、唆燃镰液征并缩含热分析确定了辩念耪韵缀簸为 RE：(HL)2(H2L)2·phennH20，探讨了鬣食物鹣成键谂点及舞谱健鹱。测定了4个配 合物豹燕倦结构，辫举黼衍射终袋裘骥，配食物[RE(H2L)fftL)(H20bh·phen4H20 (RE。Sm、Eu、Gd)酌镪个单元均为强个舞}猕糨戳的9配健懿会躲，每个既含貔中 有鼹个2*羧基闲酸水撩黻腙帮兰个水分子参与了鹦a键，同时还霄一个l，l蕊嚣眵啦 分予耩蹒个水分子游褰予晶牾申，形成了三缳鹣状的怒分予能会燃。镳懿会秘 [Dy(HL)(phen)(N03)(I-bO)2]，H20敬菇体哭4鸯艨不同，宅憝癌2-羧蓥雨黢零杨激膝、 l，l嵇嚣嗲暌、硝酸掇秘薅令东分予秘艘载9瓣锭懿会穆，瀑掇孛逐存豢～令游离懿 菇(分孑。酝套魏在窆潮凌堇援麴魏攀耀因方笈棱较。 邋遥∞0一秘稿3一Dsc燕分攒磺究了酝含躲RE：(HL)2隅Lhtphen·濑0簌4令 秀滠逮攀下躺热分解过程，和黼Kissinger法秘Ozawa浚计冀了器配合物主器分解 阶段瀚表瀚活像能。辩藩体[Eu(HL)(H2L)(H20b】2·phen-4H20猩4个手}灏速率下的三 个热分鳃阶段，分潮采鞠三种积努法瓤蹰种徽努法辩j#等潞幼办学数攒避褥了线性 翻翔处理，褥到了三个不同除段赡动力学方橼、分解娥瑷及动为学参数。 逸取6个其代表性鹣稀±与缸羰藻蔼酸零扬酝膝、l，l嵇嚣嗲啭琵食躲，采瘸生 长速率法器孢予麓发法对番菸获繇演蘧、燧孳黪登瘸藿弱，l、麦袋锈病蘩等3耱藜进 露了裳物活瞧试验。结栗表骥，6静酴杂物辫其鸯～怒秘簿蔻灞赣，蒺率 Y(磁毛b￡鹣D·5H20、Dy2(H2L)2(HL)2(phen)t2}{瓣掰秘配食稳鹣熬菌效繁羧为髑显， 寇40ug-mF‘嚣孪Y(H2L)3(H3L)t5H20辩褥茄获霉瘸麓撺菌率瓷100％，在80ugtml‘时 对烟牮淼瀑病蘸鹃韵榔藏率为100％，蘧D轮(№№@酶国№n)，2H20巍0．05ug*ml3 时辩，j、赍条锈瘸菌穗子翁发驹掷簸攀仍离达79。7％。 关键谰；稀土2-羰蒸谶酸承杨醮躲l，10．菲夥瓣食或鼓锩镰搦热分解燕物活性 {{ AbstractIn Abstract In mixed solution of aqua-ethanol，novel twelve rare earth黔k Pr,Nd，Sm，Eu, Gd，Tb，Dy,E‘Yb，Lu and Y)complexes with 2-oxo-propionic acid salicyloyl hydrazone(CtoHloN204,H3U and l，10-phenanthroline(C12HsN2,phcn)had been synthesized，The formulae RE2(HL≥z(鹣L)2-phen。nH20 were determined by elemental analysis,Ig,UV,FS，‘H NMR and thermoanalysis，The bonding character and spectra properties Were discussed．The crystals of four complexes陋Sm,Eu,Gd，Dy)Were obtained and determined by X-ray single crystal diffraction．There wefe two similar 9-coordinated complexes in every crystal unit of[RE(HL)(H2LXH20)3]zphen4H20 (RE=Sm,Eu，Gd)in which RE(m)Were coordinated by two tridentate H3L ligands and three water molecules．There were a free l，10*phenanthroline and four water in the crystal cell。The complex formed a three—dimensional network supmmolecular．For 【Dy(HL)(phen)(N03XH20)2]‘H20 monocrystal，the Dy