过渡金属Ni对Cu.doc

过渡金属Ni对Cu+-13X分子筛动态吸附脱硫性能的影响 周 林，张 强，居沈贵收稿日期： 收稿日期：2014-01-19 基金项目：国家自然科学基金 作者简介：周 林（1989-），女，江苏江都人，硕士，主要研究方向吸附法脱除汽油中硫化物；居沈贵（联系人），教授，E-mail： HYPERLINK mailto:jushengui@njut.edu.cn jushengui@njut.edu.cn （南京工业大学 化学化工学院，江苏 南京 210009） 摘　要：采用液相离子交换法制备了Cu+-13X和Ni2+/Cu+-13X分子筛吸附剂，运用X线衍射仪（XRD）、扫描电子显微镜（SEM）和傅里叶红外光谱仪（FT-IR）等对样品进行表征。通过固定床吸附实验研究Cu+-13X和Ni2+/Cu+-13X对含有噻吩(TP)、2-乙基噻吩(2-ETP)的双组分模拟汽油的动态吸附脱硫性能，以期获得过渡金属Ni对Cu+-13X分子筛动态吸附脱硫性能的影响。结果表明：Ni2+/Cu+-13X分子筛中Ni质量分数为1.54% 时，Ni2+/Cu+-13X分子筛吸附脱硫效果最佳。动态吸附实验过程中，噻吩类硫化物与两种吸附剂之间均存在π配位作用，且噻吩与2-乙基噻吩之间存在竞争吸附，而过渡金属元素Ni可以增大Cu+-13X吸附剂对2-乙基噻吩的吸附选择性；负载的Ni可以作为一种助剂，增加Cu+-13X吸附剂对噻吩类硫化物的吸附含量，在相同的实验条件下，经过渡金属Ni改性后的Cu+-13X对噻吩和2-乙基噻吩的穿透吸附量和饱和吸附量分别增加了66.9%、35.5%和24.3%、18.2%。 关键词：过渡金属离子；脱硫；动态吸附；Cu+-13X分子筛；噻吩类硫化物 中图分类号：TQ424.25；TE624.54 文献标志码：A　　　　文章编号：1671-7627（2014） Effect of transition metal Ni on dynamic adsorption desulfurization performance of Cu+-13X molecular sieve ZHOU Lin, ZHANG Qiang,JU Shengui (College of Chemistry and Chemical Engineering, Nanjing Technology University, Nanjing 210009, China) Abstract: To investigate the effect of transition metal Ni on the dynamic adsorption desulfurization performance of Cu+-13X molecular sieve, Cu+-13X and Ni2+/Cu+-13X adsorbents were prepared by liquid phase ion exchange method and characterized by means of X-ray diffraction (XRD), Scanning electron microscopy (SEM) and　Fourier transform infrared spectroscopy (FT-IR). The performances of two kinds of adsorbents for thiophene (TP) and 2-ethyl thiophene (2-ETP) were investigated by the dynamic adsorption at room temperature and atmosphere pressure. Results showed that the best adsorption desulfurization performance of Ni2+/Cu+-13X could be obtained with 1.54% of the Ni mass fraction. In the dynamic adsorption experiments, there were π complexation between adsorbents and thiophenic sulfur. Transition metal element Ni could increase the adsorption selectivity of Cu+-13X adsorbent for 2-ETP. The load of the Ni2+ could be used as an auxiliary c