含蜡原油粘弹性与蜡晶结构的关系研究-油气储运工程专业论文.docxVIP

摘要原油中已结晶蜡的量、蜡晶形态和结构是决定原油流变性的主要因素，热力和剪切 摘要 原油中已结晶蜡的量、蜡晶形态和结构是决定原油流变性的主要因素，热力和剪切 条件也正是通过影响原油中蜡晶的形态和结构对宏观流变性产生影响的。本文结合理论 基础和实验研究，对人工蜡油和含蜡原油蜡晶微观特性进行了较为全面的研究，并对人 工蜡油和原油低温条件下的宏观流变性与蜡晶的微观特性之间的关系作了进一步的研 究。本文主要利用差示扫描量热仪测量了不同含蜡原油原油降温过程中析蜡量与温度的 关系，考察胶凝过程中含蜡原油的结晶放热特性，根据实验数据确定了不同温度下含蜡 原油的析蜡量，并结合流变仪在小振幅振荡剪切的模式下，研究胶凝过程中含蜡原油储 能模量、损耗模量、损耗角等流变参数的变化规律。通过流变学测量，结合差示扫描量 热仪考察的胶凝过程中含蜡原油的结晶放热特性，探寻粘弹性参数与己析出的蜡晶质量 分数的关系，建立微观结构分形维数与析蜡量、粘弹性参数的关系模型，间接获得含蜡 原油微观结构的分形维数，从而建立了含蜡原油宏观流变性与蜡晶的微观特性之间的定 量关系。此外，测量含蜡原油的屈服值，得出了原油屈服值与已析出的蜡晶质量分数满 足指数关系。从而更深入地揭示含蜡原油的胶凝机理，希望能为含蜡原油加热管道输送 工艺的安全、经济运行以及停输再启动提供理论依据。 关键词：蜡晶；分形维数；微观结构；粘弹性 Study Study on Relationship between Viscoelastic Properties and Wax Crystal Structure of Waxy Crude Oil Wang Dan(OilGas Storage and Transportation Engineering) Directed by Prof．Li Chuanxian Abstract We all know that the content，the shape and the structure of the precipitated wax crystals are the major factors which are very important to crude oil rheology．The macroscopic rheological of crude oil is just affected by heat and shear conditions through affecting the shape and the structure of wax crystals．Therefore，Artificial waxy oil and crude oil’S microscopic characteristics are studied comprehensively in this paper combining with theoretical basis and experimental study．The relation between macroscopic rheological of crude oil and microscopic characteristics of Wax crystals in the low temperature condition is also further studied in this paper．In this paper,the relation between Wax content and temperature during cooling process of different waxy crude oil were mesured by Differential Scanning Calorimeter,the exothermic and crystallization characteristics of waxy crude oil during gelation process Was investigated，and get the Wax precipitation of waxy crude oil at different temperatures according to experimental data．Combined with the small amplitude oscillatory shear mode of rheometer,studied the storage modulus，loss modulus，loss angle changes during the gelation process of waxy crude