含碳硼烷酚醛树脂的制备及性能研究-材料科学与工程专业论文.docxVIP

北京化工大学硕士学位论文果是碳硼烷的引入确实提高了热塑性酚醛树脂的热稳定性； 北京化工大学硕士学位论文 果是碳硼烷的引入确实提高了热塑性酚醛树脂的热稳定性； (2)利用合成的oCNPF和mCNPF、过量的环氧氯丙烷在四丁 基溴化铵的催化作用下与氢氧化钠反应可以得到D．CPFE和聊．CPFE， 红外光谱中环氧特征峰的出现，表明D．CPFE和聊．CPFE的成功合成， 同时为了找到D．CPFE和m．CPFE的固化工艺，利用非等温DSC方法 外推得到D—CPFE和m．CPFE与DDS和DDM在等温下的固化条件， 完全固化后采用TGA对D—CPFE和m．CPFE的热稳定性进行了讨论， 结果是碳硼烷的存在确实提高了酚醛环氧的热稳定性； (3)利用o．碳硼烷二苯酚、多聚甲醛、己二胺(二氨基二苯基 甲烷)为原料合成含碳硼烷主链型苯并嗯嗪，考虑反应溶剂、反应时 间、后处理方式对产率及嗯嗪环成环率的影响，红外光谱中嗯嗪环特 征峰的出现，表明oCB—hda和oCB．mda这两种嘿嗪的成功合成，同 时利用不同温度下的红外光谱图，得到了oCB．hda和oCB-mda的固 化方式，固化后采用TGA对oCB．hda和oCB—mda的在900℃下的热 稳定性进行了探讨，结果是碳硼烷的存在确实提高了苯并嗯嗪的热稳 定性： 关键词：碳硼烷二苯酚，热塑性酚醛，酚醛环氧，苯并嗯嗪， 热稳定性 万方数据 ABmACTSYNTHESIS ABmACT SYNTHESIS AND PROPERTIES oF PHENOLIC CONTAINING CARBORANE ABSTRACT Phenolic res证s have excellent adhesion，heat resistance，ablation resistance and flame resistance，which widely used in coatings，adhesives， flame-retardant electronic components，aerospace and other fields．But ordinary phenolic resin is only used below 200 oC for a long time，and it is difficult to meet the current aerospace demand for high-temperature resistant,SO in order to improve the performance of high—temperature for phenolic resin，a variety of domestic and foreign scholars introduced high-temperature resistant group(such as naphthalene ring or fluorene ring)into the phenolic resin structure．Because of carborane for its cage structure and super aromatic electronic structure，the adjacent key is shortened and it Can act as”energy tank”at hi曲temperatures．So recently，many scholars use it in a variety of polymers and it is desirable to improve the high temperature properties of the polymer． This paper used carborane disphenol to synthesize a variety of phenolic resin containing carborane to study its structure and higll temperature performance，the following key elements： (1)We used D—carborane disphenol(m—carborane disphen01)，3 7％ I|l 万方数据 万方数据 万方数据 北京化工大学硕士学位论文aqueous 北京化工大学硕士学位论文 aqueous formaldehyde solution as l aw material under the action of acidic catalysts(HCl，Oxalic acid and PTSA)to synthesiz