毕业论文-铁及其氧化物对烃类结焦的催化作用.docVIP

PAGE PAGE 9 本科毕业论文 （20 届） 铁及其氧化物对烃类结焦的催化作用 专业：高分子材料与工程 摘 要 :本文以金属铁及其氧化物为催化剂催化环己烷裂解结焦。实验考察结焦温度对结焦量的影响。实验表明在反应时间为60min，环己烷热裂解反应中：以铁为催化剂时，反应温度为625℃时结焦量最大；以三氧化二铁为催化剂时，反应温度为675℃时结焦量最大；以四氧化三铁为催化剂650℃时结焦量最大。在相同的条件下铁的氧化物对结焦的催化活性远比铁强。在反应温度较高时700～725℃之间Fe和Fe3O4均出现不同程度的“板结”现象，结焦量骤减，远低于650℃时的结焦率，而Fe2O3没有明显下降；铁为催化剂反应温度为625℃在20 min～60 min时增长迅速，在60min后增长缓慢。 关键词 : 结焦； 催化；实验；热裂解 Catalysis of Iron and Oxide for Hydrocarbon Coking Abstract: The present paper, metallic iron and oxide iron as catalysts to crack cyclohexane coking. Experimental studied the effect of coking temperature on coking amount. The result show that reaction time is 60 min, the iron as catalyst, reaction temperature is 625 ℃, the amount of coking is maximum; when the trioxide as catalyst, the reaction temperature is 675℃, the amount of coking is maximum; the ferroferric oxide as catalyst, the reaction temperature is 650℃, the amount of coking is maximum. At the same condition, the catalytic activity of oxide iron is more than iron. At 700~725℃, Fe and Fe3O4 began harden, coking amount sudden reduce, lower than 650℃ coking rate, but Fe2O3 without decrease; iron as catalyst, reaction temperature is 625℃, the coking rate quickly increase at 20 min～60 min, after 60 min it increase slowly. Key words: Coking; Catalysis; Experiments; Thermal cracking 目录 TOC \o 1-4 \h \z \u HYPERLINK \l _Toc291877692 1 引言 PAGEREF _Toc291877692 \h 1 HYPERLINK \l _Toc291877693 1.1结焦的分类 PAGEREF _Toc291877693 \h 1 HYPERLINK \l _Toc291877694 1.1.1热氧化沉积 PAGEREF _Toc291877694 \h 1 HYPERLINK \l _Toc291877695 1.1.2裂解结焦 PAGEREF _Toc291877695 \h 1 HYPERLINK \l _Toc291877696 1.2裂解结焦的影响因素 PAGEREF _Toc291877696 \h 2 HYPERLINK \l _Toc291877697 1.2.1 温度对结焦的影响 PAGEREF _Toc291877697 \h 2 HYPERLINK \l _Toc291877698 1.2.2 裂解深度对结焦的影响 PAGEREF _Toc291877698 \h 2 HYPERLINK \l _Toc291877699 1.2.3 表面效应对结焦的影响 PAGEREF _Toc291877699 \h 2 HYPERLINK \l _Toc291877700 1.3现阶段结焦研究方法 PAGEREF _Toc291877700 \h 3 HYPERLINK \l _Toc291877701 1.4课题的