硅橡胶涂覆改性聚烯烃中空纤维膜的研究-材料科学与工程专业论文.docxVIP

摘 摘 要 本文研究了在聚烯烃中空纤维膜表面物理涂覆硅橡胶，讨论了涂覆条件对 聚丙烯中空纤维膜(PP)、聚乙烯中空纤维膜(PE)涂覆层、膜接触角、膜断 裂强力、气体渗透性、贮存稳定性及生物相容性的影响；通过傅里叶红外变换 仪(ATI汗T-IR)、差示扫描量热仪(DSC)、扫描电镜(SEM)和原子力显微 镜(AFM)对涂膜情况进行分析和表征，相关研究为制备高透气性、无血浆渗 漏的人工肺用膜提供理论及实践基础。 结果表明：硅橡胶含量不超过10％，催化剂二丁基二月桂酸锡的含量不大 于1．96％时涂膜均匀，不出现“分节”现象：随着涂覆液中硅橡胶含量的增加， 膜的接触角增大，膜断裂强力略有降低。 当硅橡胶含量为5％、单次涂覆时，改性后外压法测得PP、PE膜气体通量 分别为0．1405x103 m‰和0．0140x103 m3／h，较改性前膜气体通量0．1676x103 m3／11和0．0233 x103m3／lI下降最少；PP膜的表面粗糙度由改性前的35．2516nm 下降到改性后的33．6713 nm，PE膜粗糙度由之前的38．263l nm下降到 36．7583nm；这种改性条件对膜生物相溶性影响较小，涂覆后PP、PE膜对牛血 清白蛋白吸附量的增加分别为0．0100 g∥mm2、0．0013峙／mmz。 ATR／FT-IR分析表明，改性后的PP、PE膜在1087 cm1和1015 crn1处增 加了Si．O．Si伸缩振动峰；DSC分析中，涂覆改性后PP、PE膜的结晶度由于 无定型硅橡胶的存在都有所下降；红外和DSC分析共同证明硅橡胶成功涂覆 到PP、PE中空纤维膜表面。 从扫描电镜，原子力显微镜图片中可清晰看出硅橡胶致密层覆盖了PP、 PE的膜孔，可有效的防止血浆渗漏；同时改性前后的膜均可看到片晶拉伸所 致的孔结构，证实硅胶的涂覆没有改变聚烯烃基膜的基本性能，仅为表面物理 涂覆；贮存稳定性实验表明涂膜具有很好的贮存稳定性，在于态下储存最稳定。 关键词：聚烯烃中空纤维膜，硅橡胶，涂覆改性 AbstractIn Abstract In this paper,polyolefm hollow fiber membrane physically coated with silicone rubber was studied．The effects of coating conditions on the polypropylene hollow fiber membrane(PP)and polyethylene hollow fiber membrane(PE) coating， contact angle，breaking strength,gas permeation property,storage stability and biocompatibility were discussed；The coating condition was analyzed by the attenuated total reflection／fourier transfoml infl ared spectrum(ATR／FT·IR)， differential scanning calorimetry(DSC)，the manning electron microscopy(SEM) and atomic force microscope(AFM)．This paper provides a theoretical and practical basis for the preparation of artificial lung membrane with high gas permeation property and no plasma leakage． The results showed that rubber content did not exceed 20％．and the ration of dibutyl tin dilaurate was not greater than 1．96％，the”section”phenomenon was not observed；with the increase in silicone rubber content，the membrane contact angle increased，the breaking strength decreased slightly． When the silicone rubber content was 5％，the gas flux of the PP and PE membrane with primary coating film wa