硅酸根浓度智能在线检测仪的研制-机械电子工程专业论文.docxVIP

摘要现代工业用水纯度要求很高，其中硅酸根的含量是一个重要的监控项目。高效、快 摘要 现代工业用水纯度要求很高，其中硅酸根的含量是一个重要的监控项目。高效、快 速、和准确地测定工业用水中硅酸根的含量是目前水质分析的一个重要课题。本次研制 的硅酸根浓度智能在线检测仪，就是用来检测硅酸根浓度的。 本次研制的硅酸根浓度智能在线检测仪，采用化学发光法检测原理。在被检样水中 加入一定浓度的硫酸和钼酸铵化学试剂，经过化学反应后，生成硅铝杂多酸，然后再加 入发光剂鲁米诺，硅铝杂多酸与鲁米诺发生强烈的化学反应，并发出化学光。化学光的 强度与硅酸根的浓度呈正比。由光电倍增管检取化学光，转换成电信号，经过A／D转换 后，由单片机读取并进行数据处理，从而知道硅酸根浓度。 本次研制的硅酸根浓度智能在线检测仪，检测范围为0、200 ii g／L，误差±2％，可 将检测到的浓度值送LCD显示、送微打印机打印、通过4’20mA电流环送远程显示、通 过RS485协议送PC机。整个检测过程由单片机控制自动运行。检测仪可在线标定和精 度调整，通过铵键可设定系统参数，具有一定的智能。 关键词：硅酸根；化学发光法；光电倍增管：单片机：检测；控制 ABSTRACTSince ABSTRACT Since the high purity requirement of water makes the proportion of silicate in water ail important monitoring item in modem industry,the high efficiency rapidity and precise measurement of the proportion of silicate(Si03-2)in water turn out to be all important scientific subject in the present water analysis． The measurement of the silicate density in water is conducted online by chemiluminescence theory,which indicates that the sampled water added certain amounts of vitriol(H 2SO 3)and ammonium molybdate((NH4)2M04013’2H20)is added himinol after the chemical reactions take place．The sampled water containing silicate Can produce chemical light，the s仃ength of which is proportional to the silicate density．Photoelectric Magnification Tube receives the chemical light and then transfers it into voltage signal，which is input into microcontroUer after its A／D transformation．After the process of data is automatically carried out in microcontroller,the density of silicate in water being calculated out Can be displayed by LCD or typed by printer or displayed by meter in distance actuated by 4～20mA current loop or put into PC by RS一485． The entire measurement process is automatically conducted by microcontroller．Meaning that the performance Can be calibrated and detected density precision can be aajusted online and also parameters Can be set up in the process，The instrument has some intelligence． KEYBORAD：Silicate；Chemiluminescence；Photoelectric Magnifi