哈氏合金F耐腐蚀性能的改进研究-材料加工专业论文.docxVIP

甘肃工业大学硕士学位论文Abstract 甘肃工业大学硕士学位论文 Abstract Improvements on corrosion resistance of Hastelloy F alloy have been investigated in this paper．The Hastelloy F alloy shows good general resistance to corrosion and it costs lower．Some alloy elements，Re， N，Ag，Cu were joined to Hastelloy F alloy in this study．Some of its mechanical properties and some of its corrosion resistance and electrochemical properties in some typical mediums were studied． The effect mechanisms of added elements were also investigated by electron spectroscopy for chemical analysis(ESCA)and electron dispersion x—ray analysis fEDAX)．The results show that the element Cu Can improve corrosion resistance remarkably of the alloy in 30％wt boiling sulfuric acid solution，and that element Re Can improve corrosion resistance of the alloy in both of tested strong oxidzing acids and strong reducing acids or their mixture because of its good phisic—chemical effects，reducing the corrosion rate of them． It iS also indicated that element Ag could not make favorable effect if its content in the alloy was 0．87％wt，and that the effect mechanism on corrosion of element N should be further investigated．The paper forecasted there is no possibility of appearing O phase by phacomp method and proved the result by analysis on microstructure．At last， further direction of improving investigation was pointed out． Keywords：Hastelloy F alloy Corrosion resistance Electrochemical performances Corrosion rate Electron spectroscopy for chemical analysis(ESCA) Electro dispersion X-ray analysis(EDAX) Phacomp method Abstract V 甘肃工业大学硕士学位论文第一章绪言 甘肃工业大学硕士学位论文 第一章绪言 当代人类社会的文明和高新技术发展的三大基柱是：信息、 材料和能源。随着现代科学技术的发展对材料的要求日益提高， 使原有的材料越来越难以满足客观形势的需要，高性能材料对现 代科学技术的发展有着决定性意义。特别是随着航空航天、能源 电子和现代化战争武器装备等高新技术领域不断发展，对新材料 提出更高、更迫切的要求，更紧密地依赖于新材料的开发与研究。 因此世界上工业先进国家把材料作为优先发展的领域，因为材料 是一切科学的物质基础，也是改善人民生活质量所必需的一个重 要方面[1j。新材料研究的八个主要发展趋向中其一就是“高性能 化，大幅度地提高材料的比强度、韧性、耐热性、耐腐蚀性”。 而金属材料最严重最常见的损害形式是断裂、磨损和腐蚀。许多 事实已经证明，金属材料的腐蚀已经严重影响了高新技术的发展 和高性能高功能等新材料的出现，所以研究腐蚀科学技术，开发