含硫高折光率树脂的合成表征及其紫外光固化膜的性能研究-化学工艺专业论文.docxVIP

B8lOO亨 B8lOO亨 ”f 武汉他{．学院颧}。逾文 秘繇聚物在紫瓠宽照条转F的共聚露仡麟翁链戆，结采表甥： 1、PMA小姆合j|J作J}聚合；MESDMA／{i熊与MES抵聚物』B浆 僚黥与BES低聚携盔20％(wt)豹禽：鬟痰褥掰共聚龠竞圈纯 膜；丽MEPSMA和MEPSMSt则可在20％(wt％)的范¨I内 与两种低聚物熟能共聚台成光圈{也璇。 采用溶胶。凝胶法对铁酸矬丁耱(TBT)翔乙烯基二三己铤 基谴虢w蛰．2e送行闲嚣重承解镧冬出了稳定醵有轭，涎机Ti02 杂化材料的溶胶体系：讨论r影响体系稳定性的洲索”褂到 了稍器溶蔽豹簸佳祭彳孛：温度45℃，pH=O～l，正丁醇 tTBT=4：l(Volume)红外竞潞证实溶胶魑TBT与WO。20的反 应产物，透袈电予显撇镜(TEM)轰霹溶胶体系鞭辍夫，|、为 60～80rim。采用溶胶．原位聚合法柳藤他．溶胶化法分刖制舔m 了两种MMA／TBT／MAPTMS的有静I／光机纳米杂化体系；通过 形成桃理辩释了上述两种体系出TEM；姒”弛豕}}{纳水粒予结 构豢静静燎躅；尽篱迹需做受深入豹研究，似天丁折党琦夏的 袒步结鬃袭赡TiO：的母l入对摄光率的键赢舂烫漩，主土蜓其会 量的增加杂化材料的折光指数也呈上升趋势。 关键侧：尚折光率树黼，紫外光洲化，膜，仃私I／无羊JI杂化 英史摘鼗Synthesis 英史摘鼗 Synthesis and Characterization of Sulfur-containing High Refractive Index Resins and Research Oil the Performance of Their UV-curing Films ABSTRACT The method using high refractive index resin film to record hologram picture，which is commonly called See／Through Hologram，has been considered novel way in the field of holograph anti—counterfeit compared with the traditional hologram molding methods．The key realize this technique is how make the refraetive index Of those resin fiIm high possible．The main work of this paper emphasized how get resins that had high refractive index and could be cured by ultra violet radiation well studied the feasibility of their applying in the hologram anti—counterfeit filed．At the same time the primarily study introducing inorganic nano-meter particles into resin to ireprove its retractive index was carried HCl，Thiourea method was Successfully used prepare three thi01 compounds：2,2’-mercaptoethyl sulfide(MES)，2-phenyIthioethane thio|(MEPS) and 2，3·dimercaproethylthiopropanethiol(BES)．The corresponding thiol methacrylate monomers(MESDMA，MEPSMA and TPMA，respectively) of MES，MEPS and TP(thiophen01)were prepared under the reaction condition of Phase Transfer Catalysis(PTC)．Moreover another type of monomer containing styryl group(MESDMSt，MEpSMSt and TPMSt，respectively)was also obtained by the de．HCl reaction between these thioI compounds and，)． Chloromcthly