含氮氧配体的配位聚合物的水热合成、结构及性质-无机化学专业论文.docxVIP

AbstractCoordination Abstract Coordination polymers and supramolecular architectures formed through the deliberate of metals and multifuntional exodentate ligands，based on their coordination habits．have SO far spawned tremendous interests in the areas of inorganic chemistry,crystal chemistry and materials chemistry．The aim of this work iS tO design and synthesize a series of coordination polymers and study their luminescent and magnetic properties． In the first chapter,the condepts，methods，histories and developments‘of coordination polymers are concised introduced． In the second chapter，a series of metal dicarboxylate complexes with a N—donor chelate ligand 1，1 0一phenanthroline (1，1 0-phen) and its large analog 1、4、8、9．tetranitrogen-trispherie(TATP)werereported and studied the influences ofthe size of the aromatic chelate ligands on the framework structures of their coordination polymers，namely【Co(phen)(oba)】n0．5nn20(1)，[Ni(phen)(oba)】．-0．5nH20(2)， 【C02(H20)(TATP)2(oba)2]．2nH20(3)，and[Ni2(H20)(TATP)2(obahl．2nH20(4) (oba=4,4’oxybis(benzoate))．With smaller L=phen，both l and 2 are one—dimensional helical chains．while with larger L=TATP．both 3 and 4 are two．dimensional networks．These results indicate that the changes of the size of the rigid aromatic chelate ligands，adapting the coordination modes of dicarboxylatc ligands：from a chelating to a monodentate modes accompanied by incorporation of the coordinating water，may have significant effect on the framework structures of the coordination polymers． In the third chapter,Lantllanide C00rdination polymers with the formula 【Ln(pydc)2]·H20(Ln；La，5；Nd，6；pydc=3,4-pyridinedicarboxylate)and 【Ln(pydc)(ina)(H20)2】(Ln=Sm，7；Eu，8；Tb，9；Dy,10；pydc一 2 3,4一pyridinediearboxylate，ina isonicotihate)were synthesized by treating Ln(III) nitrates with 3．4-pyridinedicarboxylic acid under hydrothermal conditions． Single．crystal and powder X—ray diffraction studies indicate that these lanthanide CO(Irdination polymers adopt two differe