贵金属元素在复膜树脂上的分离富集行为及其原子吸收光谱法测定的研究-分析化学专业论文.docx

白在j缸贵金属元素在复膜树／1％_k的分离富集行为及其原子吸收光谱法测定的研究第三章研究了PVC．双硫腙复膜树脂的合成及其分离富集金 白在j缸贵金属元素在复膜树／1％_k的分离富集行为及其原子吸收光谱法测定的研究 第三章研究了PVC．双硫腙复膜树脂的合成及其分离富集金 的最佳条件。在pH为1．5的盐酸介质中，金能定量吸附在PVC一 双硫腙复膜树脂上，用O．5mol／L硫脲一0．1mol／L HCI溶液洗脱，火 焰原子吸收光度法测定，回收率均在95．4％～106．7％，RSD4．5％。 此法用于地质样品中金的测定，结果令人满意。 总之，本文通过大量深入、系统的实验研究，制备了对贵金 属元素金和钯具有高选择性、高吸附容量的复膜树脂。这种树脂 在很大程度上克服了螯合树脂合成困难，应用受到限制的缺点； 同时解决了螯合剂负载树脂抗酸碱能力弱以及稳定性较差这些难 题。并且应用所制各的复膜树脂，建立了常规离线色谱柱和自动 在线流动注射分离富集贵金属元素的新方法，具有一定的理论和 实际应用价值。 关键词：复膜树脂，分离富集，火焰原子吸收光度法，流动注 射分析法，测定，金，钯 AbstractOn Abstract On the basis of numerous references，author firstly has synthesized two kinds of double membranes resin，namely PVC—dithylglyoxime and PVC—dithizone．Using double membranes resin that was packed into chromatographic column stationary phase，the separation and concentration behavior of gold and palladium in the extraction chromatography has been studied， respectively,and then new methods for analysis and determination of trace gold and palladium have been established．At the time， PVC—-dithylglyoxime has been packed into the micro··columns that were used in the system of FI—FAAS，in which on—line concentration and separation and determination of palladium have been studied． Experiments showed that hi曲analysis speed and good selectivity to palladium was obtained in this automatic FI-FAAS system． This paper consists ofthree chapters： In chapter one，the synthetic procedure of PVC—dimethylglyoxime double membranes resin was described． PVC—dimethylglyoxime double membranes resin that was packed into conventional packed column was used to separate and concentrate palladium in tails．Palladium was eluted using 10％glycol-2％sodium hydroxide as eluent,and then determined by atomic a_bsor面on spectrometry．The recovery percent Was 92．4％一98．8％，RSD2．9％． In chapter two，a flow injection，including sequent and reversed double columns，on-line separation and concentration-flame atomic o／prectous 竺丝尘型!竺!竺!竺竺竺竺!型生堡竺型!竺型型i absorption spectrometric method for determination of trace palladium in