可用于燃料油脱硫新型MOF材料合成-化学工程与技术专业毕业论文.docxVIP

北京化工大学硕士学位论文BT之间存在酸碱交互作用，导致吸附量提高。MIL．101．Cr-S03Ag．10 北京化工大学硕士学位论文 BT之间存在酸碱交互作用，导致吸附量提高。MIL．101．Cr-S03Ag．10 吸附BT符合拟二级动力学模型，同时MIL-101一Cr-S03Ag．10具有很 好的再生性，至少可以重复利用5次。 3．针对DBT的吸附测试。采用间歇吸附法，研究Cu．BTC、 Cu．MOF．74和PCN-10这三种MOFs对DBT的吸附能力。测试结果 表明：在初始浓度为1000ppmS时，PCN．10的吸附效果最好，吸附 量达到75．24 mgS·g～MOF，远高于其他吸附材料。这是由于PCN-10 中的不饱和金属位和／i；．7【络合作用导致的。对于低浓度下的DBT， PCN．10具有很好的脱除效果，脱除率达到99％，吸附后的浓度达到 欧五标准。PCN-10具有很好的再生性，至少可以重复利用五次。 关键词：金属有机骨架材料，有机硫化物，吸附，再生 II 万方数据 ABSTRACT ABSTRACT SYNTHESIS OF METAL oRGANIC FRAMEWoRK FoR Desulfurizafion of FUEL OIL ABSTRACT The organic sulfur compounds in the fuel oil can be converted to sulfur oxides，which will endanger our environment and health．Therefore， it is urgent to remove the organic sulfur com—pounds efficiently in the fuel oil．Metal organic frameworks，as one type of porous materials with high specific surface area,high porosity and good thermal stability,have exhibited promising applications in liquid phase adsorption and separation，gas storage and separation，catalysis，medicine，fluorescence． In this work，several new MOFs were selected and synthesized for the organic sulfur compounds adsorption．With regard to benzothiophene (BT)and dibenzothiophene(DBT)，we studied these organic sulfur compounds adsorption on these materials．The specific research contents were as follows： 1．The synthesis of MOFs．Making use of our existing equipments， we adopts hydrothermal synthesis method for synthesizing different kinds IlI 万方数据 万方数据 万方数据 北京化工大学硕士学位论文of 北京化工大学硕士学位论文 of MOFs，such as MIL-l O 1-Cr-S03H，MIL-1 0 1一Cr-S03Ag，Cu-BTC， MOF一74一Cu and PCN-1 0．but in this work the synthesis of PCN-1 0 has the advantages of short time and large yield．The characterization of MOFs included powder X ray diffraction(XRD)，scanning electron microscope(SEM)，Fourier transform infrared spectra(FT-IR)， thermogravimetric analysis(TGA)and specific surface area(BET) 2．The adsorption of BT．We studied the BT adsorption on M／L一1 0 1一Cr-S03H and MIL一1 0 1-Cr-S03Ag by the batch adsorption．Th