水溶性有机质对茶园土壤氟形态影响.PDFVIP

安徽农业大学学报, 2012, 39(3): 389-393 Journal of Anhui Agricultural University 网络出版时间：2012-4-28 8:07 [URL] /kcms/detail/34.1162.S0807.002.html 水溶性有机质对茶园土壤氟形态的影响 1, 2 2 2 1 1 郜红建 ，金友前 ，董艳红 ，宛晓春 ，张正竹 (1. 安徽农业大学园艺学博士后流动站，合肥 230036 ；2. 安徽农业大学资源与环境学院，合肥 230036) 摘 要：采用元素分析与傅里叶变换红外光谱相结合的方法分析了腐熟鸡粪中水溶性有机质(dissolved organic matter ，DOM)的结构及组成，通过溶液连续提取- 电位分析法分析茶园土壤中氟的形态及含量。结果表明，腐熟鸡 粪 DOM 中C 、O 、H 和 N 元素含量占元素总量的 93% ，其中C 和 O 的含量大于 H 和 N ，C/H 和 C/N 较大，C 、H 饱和度低，含有较多羧基、醛基、酮基等不饱和度高的物质。水溶态和有效态氟含量随外源 DOM 添加量的增加而 降低，呈负相关关系；而土壤铁锰结合态氟、有机结合态氟含量则随外源 DOM 添加量的增加而升高，呈正相关关 系。外源DOM 的加入可降低茶园土壤水溶态和有效态氟含量，提高了铁锰结合态氟、有机结合态氟含量，降低氟 的生物可利用性。 关键词：水溶性有机质；结构；组成；土壤氟形态；影响 中图分类号：S571.1; X142 文献标识码：A 文章编号：1672−352X (2012)03−0389−05 Influences of dissolved organic matter on fluoride fractions in soils 1, 2 2 2 1 1 GAO Hong-jian , JIN You-qian , DONG Yan-hong , WAN Xiao-chun , ZHANG zheng-zhu (1. Post-doctor Institute of Horticulture; Anhui Agricultural University, Hefei 230036; 2. School of Resources and Environment, Anhui Agricultural University, Hefei 230036) Abstract: The structure and composition of dissolved organic matter (DOM) extracted from the composted chicken manure were analyzed using elemental composition analysis and Fourier transform infrared spectroscopy (FTIR) methods, and the impacts of this DOM on the fractions of fluoride in soil were analyzed by using sequen- tial extraction procedure and potentiometric analysis methods. The contents of carbon and oxygen were higher than that of hydrogen and nitrogen, accounting for 93% of all