醇胺类离子液体的合成及表征-河北工业科技-河北科技大学.PDF

27 5 河 北 工 业 科 技 Vol. 27, No . 5 2010 9 H ebei Journal of Industrial Science and T echnolog Sept. 20 10 : 2010) 1 2 1 1 1 1 , , , , , ( 1. 河北科技大学化学与制药工程学院, 河北石家庄 0500 18; 2. 河北科技大学资产管理处, 河北石 家庄 050018) : 由乙醇胺二乙醇胺三乙醇胺提供阳 子, 甲酸乙酸乳酸提供阴 子, 合成了一系列醇 胺类 子液体, 并对其进行了核磁共振氢谱和红外光谱表征并确认将常规水浴法冰水浴法微 波法进行比较, 并对水浴条件下反应温度反应时间对收率的影响进行了考察最佳反应条件如 下: 反应时间为20 h, 水浴温度为5 : 子液体; 合成; 表征 : O645. 4 : A S nthesis and characterization of h drox l ammonium ionic liquids 1 2 1 1 1 1 JI Junr ong , YUAN Haitao , WA NG Jian ing , FU Linlin , DU Zhenlei , HU Yongqi ( 1. College of Chemical and Pharmaceutical Engineering , H ebei Universit of Science and T echnolog , Shijiazhuang H ebei 050018, China; 2. Department of A ssets Management, H ebei Universit of Science and T echnolog , Shijiazhuang H ebei 050018, China) Abstract: A series of h drox l ammonium ionic liquids were s nthesized from cation coming from ethanolamine, diethano lamine, and t riethanolamine and anion from lactic acid, acetic acid and formic acid, and confirmed b 1 NMR and 13 C NMR. H This research made a comparison among conventional wat erbath method , ice waterbath method and m icrow ave w aterbath met hod. In addtion, an investigation of the effect of waterbath temperature and time on recover rate w as carried out. The re sults suggest that t he optimal s nthesis condit ions are 5 and 20 h. Key words: ionic liquids; s nthesis; characterization , , , [ 1] , [ 2] , , , , ( [ 37] ,