混杂改性聚丙烯复合材料研究-高分子材料专业论文.docx

塑垩三些查兰堡主堂垡堡苎 塑垩三些查兰堡主堂垡堡苎 一———i!墨 Study on the IIybrid Composites of Polypropylene ABSTRACT Blending modification，filling modification a11d hybrid modification of PP are studied in t11is p印eL PP／HDPE，PP／POE and PP／PP conlposites are studied in blending modification． The resuhs show that HDPE and PP botll can improve tlle toughness of PP，and t11e tensile strcngth aIld flexible s仃ength a linle；POE caIl improve tlle tougllIless of PP obviously，but its tensile s廿engm and nexible strc璎m descend much． In删ng modification，也e mechaIlical propenies of nano-CaC03栅ed州tll homopolymerized PP and copOlymerized PP are compared．The resuns show也at a proper qllamity of nallo-caC03 c髓reinforce and tou曲cn PP at a small extent．The TEM photographs show tllat me n觚小CaC03 particles can be dispersed in nano。scale into t11e m删x of PP by melt blending metllod．And tlle supemne tal卯P，mic卯P， w01lastollit卯Psuperfine wollastonite／PP，superfine talc／nano—CaC03／PP，superfine tak，supe血峙wollastoIlite，PP composites are stIldied．Ttle resuns show mat at low content of superfine“c，it also c觚reinforce锄d to时1en PP like n锄o-CaC03，a11d thc tensile s订engm and nexible st∞ngtll are improVed rlo切Ibly；IIlica can inlpr0Ve the tcnsile strengm and nexible咖englll 0f hDmopolymeri∞d PP or copolymerized PP aIld也e reinforcement of copolymerized PP are more notable也肌homopolymerized PP；For copolyIIlerized PP’me钯nsile s仃engIh，nexible妣nglll她d notched impact s恤ngm of superfine wollast0Ilite short助er filled PP are bcttcr协an common wollastonite mled PP；1k synergistic e腩cts of superfine talc粕d n锄o-CaC03 is not evident；111e s”ergistic e仃ects of superfine talc锄d superfine wollast011ite display mainly tllat nle nexible streng：Ill of tlle PP，superfine talc／supemne woll∞tollite composites arc impr0Ved obviously． In h)rbrid modification，thc c优珥，0sitE爆weIe pr印ar司by melt blending iIl tv旧 screw懿tnJde￡For the a