甲基丁烯醇的VUV同步辐射光电离解离实验与理论研究-同步辐射及应用专业论文.docxVIP

AbstractAbstract Abstract Abstract The dissertation mainly introduces the experimental and theroretical studies of the biogenic secondary organic aerosol precursor 2-Methyl一3一buten一2·ol，with tunable synchrotron radiation dissociative photoionization． In the Inst chapter,it firstly introduces the source and classification of SOA．Some biogenic volatile organic compounds(BVOCs)and their oxidation mechanisms are described．The basic conceptions on photoionization and photodissociation，including adiabatic ionization energy,vertical ionization energy,apperance energy,and the fundamental phtotodissociation mechanism are briefly introduced．The common experimental and theoretical methods are also introduced in the third section．Finally, the photoionization studies of some BVOCs are described． In the second chapter,a summary is given on the characteristics and applications of synchrotron radiation，the parameters of storage ring of National Synchrotron Radiation Laboratory(NRSL)．It introduces the structure of the atomic and molecular physcis beamline and endstation．The undulator beamline can provide the tunable VUV light in the energy range of 7．5—124eV．An introduction is also given about the installation and testing of the gas filter system．Finally,the formation principle of molecular beam and the operating principle of the mass spectromter are described． In the third chapter,the theoretical methods used in this thesis are briefly introduced，including the quantum chemistry calculation methods，transition state theory and potential energy surface． In the forth chapter,the biogenic secondary organic aerosol precursor 2一Methyl一3·buten-2一ol is experimentally and theoretically studied with tunable VUV synchrotron photoionization in the photon energy range of 9～1 5．5 eV．The IE of MBO iS calculated to be 9．70 eV with the G383 method which is in reasonable agreement、Vith the experimental result·(9．50 4-0．01 eV)．At the same time，the appearance energies of C5H90+，C4H70+，CsH94-，C3H70+