甲苯液相催化氧化动力学和反应器网络模拟与优化-化学工程专业论文.docx

AbsnactAbstract Absnact Abstract Both benzoic acid and benzaldehyde are important organic raw materials in the industry．Liquid-phase oxidation of toluene by air is a green process to produce benzoic acid and benzaldehyde because of mild reaction condition,higll yield and safety． This work was to study the kinetics characteristics ofliquid-phase air oxidation of toluene in a stirred tank reactor by using cobalffmanganese／nickel in naphthenic acid as catalyst and bcnzaldehyde锄initiator．In order to clarify the reaction mechanism of liquid-phase oxidation of toluene,the initiation and transfer of chain reaction,and effects of intermediate product on oxidation reaction,it iS necessary to study the reaction kinetics of toluene oxidation．The experiments Were carried out at different stirred rate．reaction temperature and addition amount ofbenzaldehyde．Thc variation ofreactant and product concentration with reaction time under reaction temperature of 155、160、165、170℃Was obtained．Asuitable reaction network and kinetics model of liquid-phase oxidation of toluene was proposed and the kinetics paramerters Were determined based on the experimental results． A reactor model for gas-liquid two-phase bubble column oftoluene oxidation Was buiIt on the kinetics model and reactor flow model．The established model predicts the conversion,selectivity and yield of the industrial process wi饿the relative differences less than 5％．which indicate that the established model is reliable and could be used to predict the outcome．Then the influence ofthe operating parameters such as toluene flux，operating temperature，operating pressure，temperature of input air and input toluene on the production index(the conversion,the selectivity and the yield)was investigated．The toluene flux，operating temperature,operating pre锅ure戳the remarkable factors． Finally,a superstructure model of reactor network Was proposed OU the basis of continuous stirred-tank reactors(CSTR)and plug·flow reactors gFR)．A multilevel-h