激光诱导自蔓延反应合成准晶和非晶材料-材料加工工程专业论文.docxVIP

辽宁工程技术大学硕士学位论文摘 辽宁工程技术大学硕士学位论文 摘 要 注意到构成Ti—zr基准晶合金体系和Zr基大块非晶合金体系的主要 组元之间具有很大的负混合焓，因而能够发生很强的放热反应。利用这 一特点，我们首次开展了激光诱导自蔓延反应合成Ti_zr_Ni系准晶材料 和Zr-A1一Ni-Cu系jE虽复盒挝抖的探索研究。 对Ti_Zr-Ni系准晶材料我们研究了激光点火功率参数对同一种组分 的组织、孔隙度、显微硬度的影响。此外我们还研究了不同组分的材料 在相同的激光点火功率下合成产物的区别。通过研究我们发现合成产物 主要是由准晶I_相、a(Ti／Zr)固熔体相及具有MgZn2晶体结构的Laves 相所组成。 对z卜A1—Ni—Cu合金系我们同样通过改变工艺参数及组分来进行研 究。研究表明反应合成产物主要是由非晶、Zr3A12和Zr2Cu型金属问化 合物所组成。 ／v／ √ 关键词：激光诱导自蔓延准晶非晶显微硬度 。 堑童三堡堡垄查：掌堡土堂堡垒圣 堑童三堡堡垄查：掌堡土堂堡垒圣 里 Laser-induced SeH．．propagating Reaction Synthesis of Quasicrystal materials and Amorphous materials Abstract Noticing that strong exothermic reaction due to large negative enthalpy of mixing can occur among major components of Ti-Zr-based Quasicrystal alloy s3，stems and Zr．based bulk Amorphous alloy systems．we developed for the first time a new technique for fabricating both Ti—Zr-Ni systems Quasicrystal materials and Zr．Al，Ni．Cu systems Amorphous-based composite materials using Laser-induced Self—propagating Reaction Synthesis rLSRS)． In this Paper,the microstructure of LSRS was systematically studied by using XRD and TEM for both the Laser-induced Self—propagating Reaction Synthesis of Ti—Zr．Ni systems Quasicrystal materials and Zr-AljNi-Cu systems Amorphous-based composite materials．Furthermore，influence of laser power on the microstructure，properly and microhardness of LSRS products was also investigated．The study shows that the products of Quasicrystal materials mainly consists ofⅨ一(Ti，Zr)solid_solution，I-phase，and C14一Laves phase with the MgZn2 structure type．And the products of Amorphous materials consists of amorphous，Zr3A12 and Zr2Cu phases． Keywords：Laser-induced Self-propagating reaction Quasicrystal Amorphous microhardness 辽宁工程技术大学硕士学位论文1．前言 辽宁工程技术大学硕士学位论文 1．前言 1．1准晶概况 准周期晶体材料(Quasicrystal)简称为准晶材料是一种新型的金属材 料。所谓准晶是指同时具有长程准周期平移序和非晶体学旋转对称的固态 有序相1031。人们在准晶材料的合金成分、制备、结构特征和模型及性能方 面进行的大量的实验