共基质型微生物燃料电池降解偶氮染料与产电-环境工程学报.PDF

第 11卷　 第 8期 环 境 工 程 学 报 Vol. 11,No.8 2 0 1 7 年 8 月 Chinese Journal of Environmental Engineering Aug . 2 0 1 7 共基质型微生物燃料电池降解偶氮染料与产电 1 1 2,∗ 1 2 1 虞洋 ,胡淑恒 ,程建萍 ,孙秋阳 ,郭婧 ,汪家权 1. 合肥工业大学资源与环境工程学院,合肥230009 2. 合肥工业大学机械与汽车工程学院,合肥230009 摘　 要　 通过构建一个双室微生物燃料电池,以葡萄糖-偶氮染料(甲基橙)混合物为基质,探讨甲基橙初始浓度以及 pH 对 -1 甲基橙在阳极室中同步脱色和产电性能的影响。 结果表明,当葡萄糖浓度为 1 000 mg ·L ,甲基橙初始浓度为 -1 300 mg ·L ,pH =7.00 时,甲基橙脱色率在6 h 已经超过了90.00% ,且在1000 Ω 外阻下最大输出电压能达到0.587 V。 而厌氧对照下,脱色率仅为32.06% ,MFC能显著提高脱色效果。 从甲基橙降解前后紫外可见光谱扫描图上看出,甲基橙的 脱色主要依赖于降解脱色而不是微生物的吸附,且脱色过程有中间产物生成。 关键词　 微生物燃料电池;共基质;甲基橙;产电 中图分类号　 X703.1　　 文献标识码　 A　　 文章编号　 1673-9108(2017)08-4868-06　　 DOI　 10.12030/ j.cjee.201602120 Decolorization of azo dye and bioelectricity generation by microbial fuel cell with co-substrate 1 1 2,∗ 1 2 1 YU Yang ,HU Shuheng ,CHENG Jianping ,SUN Qiuyang ,GUO Jing ,WANG Jiaquan 1.School of Resources and Environmental Engineering,Hefei University of Technology,Hefei 230009,China 2.School of Mechanical and Automotive Engineering,Hefei University of Technology,Hefei 230009,China Abstract　 A two-chamber microbial fuel cell (MFC) containing a mixture of glucose and methyl orange was constructed to investigate the influence of initial methyl orange concentration and pH on its synchronous decolori- -1 zation and electricity generation in the anode chamber. The decolorization efficiency of 300 mg ·L methyl or- ange exceeded 90.00% over 6 h,with a maximum voltage output of0.578 V under 1000 Ω external resistance -1 being recorded at a