环氧树脂固化剂的微胶囊化及其对环氧树脂固化行为的影响-材料科学与工程专业论文.docxVIP

环氧树脂固化剂的微胶囊化及其对环氧树腊固化行为的影响Abstract 环氧树脂固化剂的微胶囊化及其对环氧树腊固化行为的影响 Abstract An epoxy resin-based system containing microencapsulated curing agents was employed to prolong its shelf life by separating the curing agents from epoxy resin during storage．When the temperattⅡe increased to a desired point，the capsules were broken and the curing agents would be liberated to CBre epoxy resin． Obviously,from a practical standpoint,the polymers used to encapsulate the curing agents of an epoxy resin should possess a controllable softening-point or suitable decomposition temperature besides good compatibility with epoxy resin． Suitable wall materials and COre curing agents were reported in patents．Examples of wall materials include，among others，gelatin，agar,methylcollulose,starch,starch degradation products，vinyl polymers and so on．The curing agents capsulated in protective polymers may be any material that reacts诵tll epoxy groups．This includes the amines，amino-containing polyamides，acids，acid anhydrides et a1． Microcapsules containing curing agent，2-phenyl imidazole(2PZ)，for diglycidyl ether of bisphenol A(DGEBA)epoxy resin,are prepared by solid··in-oil··in-water(s／o／w)emulsion solvent evaporation technique,using poly (methyl methacrylate)(PMMA)as polymeric wall．The mean particle size of the microcapsules and the concentration of 2PZ are about 10 tan and nearly 10 wt％， respectively． Onset cBre temperature(To)and peak temperature(7≯of EP／Micr020 system appear to increase nearly 30 oC and 10 oC respectively than EP／2PZ system due to the increased reaction energy of CIHe(昂)．The former Can reserve even more than six months under room temperature while the latter is cured after only a week． Curing kinetic parameter reaction order行ofEP／2PZ system，EP／Mier020 system are quite closed,which illuminates that cure reactions of two samples are preceding conformably． A two—step initiation mechanism during curing process is considered,the first is assigned to adduct formation while the second one