间苯二酚的低污染合成工艺开发探索-应用化学专业论文.docxVIP

重庆大学硕士学位论文 重庆大学硕士学位论文 英文摘要 ABSTRACT Resorcinol，which is all important fine organic intermediate，has been widely used for many fields such aS agriculture，dyestuff,dope，medicine,adhesive and latex．With the rapid development ofautomobile industry,the yield oftyre will be enlarged SO much that the output ofresorcinol produced at home carl’t meet the demand in the market．In another ease，the technics for resoreinol at home gives low resorcinol yield but too many pollutants which pollute the environment seriously．With the higher and higher requirement for quality of resorcinol and more and moTe attenfion on environmental protection，the research on new technics ofresorcinol having better environmental effect is very needed． A process for the preparation of resoreinol from diisopropylbenzene(DIPB)has been introduced in this paper．And a feas佑le technics is proposed as the followings：Firstly, DIPB is oxidized for about 20～25 hours to the diisopropylbenzene dihydroperoxide (DHP)or diisopropylbenzene hydroxyhydroperoxide(HHP)under anhydrous， non-alkaline conditions wi廿1 oxygen at 85℃and the remaining unreacted DIPB is recycled to the feed stream for further hydroperoxidation．Secondly,the hydroperoxidation product extracted with 4％NaOH and reextracted with methyl isobutyl ketone(MINK)at about 80。C is pretreated with hydrogen peroxide．Last，the drying product is decomposed at 50℃for about 20 minutes in the presence of a catalyst boron trifluoride，the activity of which’is SO hi曲that significantly small anaount of it aS low as 40 p g will work．and extracted耐m 50ml×3 aether to produce the rude resorcin01．Every time we can achieve about 20％yield and about 40％final yield．The effect of every factor on the experimental results has been studied．The results show that the presence of water will bring out more subsidiary reactions and the control on temperature is important in the co