高效液相色谱串联质谱法快速测定氟虫腈及其代谢物在花生-现代农药.PDF

第17 卷 第6 期 现代农药 Vol.17 No.6 2018 年12 月 Modern Agrochemicals Dec. 2018 ◆ 环境与残留 ◆ 高效液相色谱串联质谱法快速测定氟虫腈及其 代谢物在花生和土壤中残留 冯义志，张爱娟，李文平，刘 伟，梁 林* 山东省农药科学研究院山东省化学农药重点实验室，济南 250033） （ 摘要：建立了花生和土壤中氟虫腈及其代谢物的残留分析方法，进行田间试验，明确氟虫腈在花 生和土壤中的残留量及残留消解动态。 试验结果表明，氟虫腈在土壤中消解动态符合一级动力学 方程， 半衰期为11.6～16.1 d 。 花生仁和植株样品中氟虫腈最终残留量小于最低检测质量分数 （0.005 mg/kg） ，低于我国残留限量标准（0.02 mg/kg） ；土壤中氟虫腈的最终残留量不超过0.450 mg/kg ，花生壳中氟虫腈的残留量不超过0.138 mg/kg 。 该方法快速简便，准确可靠。 关键词：氟虫腈；代谢物；花生；土壤；残留；消解动态 中图分类号： ＋ 文献标志码： ： TQ 450.2 63 A doi 10.3969/j.issn.1671-5284.2018.06.011 Determination of the Residual Fipronil and Its Metabolite in Peanut and Soil by HPLC-MS/MS Feng Yi-zhi, Zhang Ai-juan, Li Wen-ping, Liu Wei, Liang Lin* (Key Laboratory for Chemical Pesticide of Shandong Province, Shandong Academy of Pesticide Sciences, Jinan 250033, China) Abstract: To clear the residual behavior of fipronil after its application in peanut field, a residual analytical method of fipronil and its metabolite in peanut and soil was developed. Fipronil and its metabolite were analyzed by HPLC-MS/MS. Field experiments were conducted in three different locations during two years. The results showed that the half-lives of fipronil were 11.6-16.1 d in soil. The final residues of fipronil in peanut kernel and peanut plant were all below 0.005 mg/kg, The ultimate residues in soil and peanut shell were no more than 0.450 mg/kg, 0.138 mg/kg, respectively. The method was fast, simple, accurate and reliable. The final residues of fipronil in peanut kernel was below the MRL value (0.02 mg/kg). Key words: fipron