脉冲激光轰击法连续制备纳米合金，纳米碳及其聚合物杂化材料的研究-高分子化学与物理专业毕业论文.docx

Y-- Y-- 619152 福建师范大学硕士学位论文 内容提要 采用本课题组建立的脉冲激光轰击浸于流动液相中固体靶 (PLA-IWSFL：Pulsed Laser Ablation at the Interface of Target Submerged in Flowmg Liquid)的新方法，成功制得纳米NiMnCo、 FeNiMn、FeNi和NiMn四种合金／乙醇溶胶及其纳米合金粉末并 对其进行表征和分析；分别以水、无水乙醇、乙酸乙酯、苯、1 ‰聚苯乙烯苯溶液五种极性不同的溶剂(液)为流动相，石墨为 碳靶，采用PLA．IWSFL法成功制得五种不同的纳米碳溶胶及其 相应的纳米碳粉末，分析表明，极性不同的溶剂(液)作为流动 相，其组成与性质强烈地影响到纳米碳粒径及其分布、溶胶稳定 性以及光谱学特性；利用PLA-IT／SFL法采用不同合金触媒粉与 石墨粉不同比例混合和预制纳米合金溶胶作为流动相的两种实验 方法成功合成了纳米碳一纳米FeNi合金混合纳米材料，分析表 明，在石墨靶中预先混有合金触媒粉对制备纳米碳能够起到某种 催化作用，而预制纳米合金溶胶作为流动相对制备纳米碳的催化 作用不甚明显，其还有待进一步的深入研究；采用PLA-IT／SFL 法成功制备出五种不同百分含量的纳米碳一聚苯乙烯杂化材料，分 析表明，纳米碳能够与聚苯乙烯大分子的苯环侧基形成一定的共 轭效应，该共轭效应使聚苯乙烯材料的玻璃化温度明显降低、塑 性有所加强、耐热稳定性有所提高。 关键词：脉冲激光轰击，纳米合金，纳米碳，纳米碳一聚合物杂化材料 瘩经作者、导师同蠢 福建师范大学硕士学位论文Abstract 福建师范大学硕士学位论文 Abstract Nano—NiMnCo，FeNiMn，FeNi and NiMn alloy／ethanol sol as well as their nanoparticles were successfully prepared by the novel experiment method established and developed by our group，which is Pulsed Laser Ablmion at the Interface of Target Submerged in Flowing Liquid(PLA-IT／SFL)．Five kinds of reagent or solution with the different polarity such as water,ethanol，ethyl acetate， benzene and l‰polystyrene ofbenzene were selected as the flowing liquid．and the graphite target was selected as the solid one，SO the five kinds of nano—carbon sol and their corresponding carbon nanoparticles were also successfully prepared by the PLA—IT／SFL method．The characterizations and analysis show that the nano—carbon particles’size，distributing，the sol’S stability and its spectroscopy speciality are strongly affected by the constitutes and properties of the flowing liquid with different polarity．With the exploiting of two plans，one is that the alloy powder was mixed into the graphite target in advance with the different proportion；another is that the nano alloy／ethanol sol prepared in advance was selected as the flowing liquid，the composite of the nano—carbon and nano—FeNi alloy was successfully prepared by the PLA—IT／SFL method．The characterizations and analysis show that in the fir