脉冲激光烧蚀钼靶制备化合物纳米颗粒及其性能研究-材料学专业毕业论文.docxVIP

万方数据 万方数据 摘 要 MoS2 和 MoC 在光电和催化领域具有重要的应用，新型合成工艺会带来独特 的结构和奇特的性能。苯问利用金属钼靶在激光作用下得到了 MoS2 无机富勒烯 结构和 MoC 纳米颗粒。主要研究成果如下： 1.利用纳秒脉冲激光液相法，以二甲基三硫醚(CH3S3CH3)为硫源，烧蚀钼靶 初步得到了二硫化钼纳米结构。通过对比不同反应活性纯硫源实验研究了硫源对 最终产物的影响；通过后续溶剂实验确定有机溶剂与水溶剂体系会阻碍反应发 生；通过研究不同表面活性剂确定在本实验体系下表面活性剂不会对对产物产生 影响。 2. 利用毫秒脉冲激光活性气氛法，以二甲基三硫醚(CH3S3CH3)为硫源，烧蚀 钼靶得到了纯净的无机富勒烯结构二硫化钼纳米颗粒。通过对比不同激光能量、 冷却速度及硫源活性研究了对最终产物的影响并得到生长机理；并且把它应用为 光响应器件，在 500K 温度下得到了响应迅速、循环稳定的光响应性能。 3. 利用纳秒脉冲激光液相法，以正己烷为碳源，烧蚀钼靶得到了纯净的 MoC 纳米颗粒。通过对比不同激光能量实验研究了能量对最终产物的影响；通过后续 溶剂实验确定不同结构的碳源对最终产物影响。 关键词：二硫化钼；无机富勒烯结构；光探测器；碳化钼(MoC)；脉冲激光烧 蚀法。 ABSTRACT MoS2 as the typical transition metal sulfide semeconductors, which have been proved to own great optical and electrical properties. They play an important role in lots of hot research area, especially in photoelectric conversion device. The synthesis and the application of inorganic fullerene nanoparticle just are the hottest. Transition metal carbides such as MoC have shown catalytic properties resembling group VIII metals in a number of hydrogen-involved reactions. But up to mow, the bottleneck emerge that be lack of structural diversity, limited synthesis methods and slow in performance improvement. Well it’s belived the bacis solution for this bottleneck is the effective combination of the research of both materials synthesis and application，to design structure based on the requirement of its application.In this paper, some preliminary exploration and research has been carried out based on the requirements of newly materials synthesis methods and actual application performance would be focused. The main research results are as follows. We demonstrated that ns pulsed laser ablation of molybdenum target in liquid is a facile and rapid strategy for the fabrication of MoS2. The crucial factors for control final nanostructures include solvent, surfactant, and sulfur resourse reactivity.. We demonstrated that ms pulsed laser ablation of molybdenum target in reactive gas is a facile and rapid strategy for the fabrica