锰对热镀锌镀层组织与性能影响的研究-材料学专业毕业论文.docxVIP

湘潭大学硕士学位论文 湘潭大学硕士学位论文 ABSTRACT II II Abstract Hot-dip galvanizing has been widely used in various industries due to its good corrosion resistance which could be affected by many factors, such as alloying element in zinc bath and in the substrate. This work mainly studies the effect of the alloying element manganese both in the bath and in the substrate on the growth and morphology of galvanizing coatings. It was found that much power dross deposited in the bottom of the zinc pot after adding manganese to zinc bath. The number of the power dross increases with the increase of the content of manganese in the bath. The manganese in the bath can retard the growth of the galvanizing coatings and change the coatings morphology whether aluminum is added to the zinc bath or not. The colorized surface can be seen after the samples dipped in the Zn-Mn bath. The coating consists of the compact δ phase and the ζ phase. The manganese in the bath can promote the growth of the δ phase and inhibit the growth of the ζ phase. The dross mainly consists of the Mn-rich ζ phase. When dipped in the Zn-Mn-Al bath, the coatings consist of the δ phase and the fragmental Mn-rich δ phase. The δ phase changes from fragmental to compact after manganese is added to the bath. The most common method to overcome the silicon reactivity is adding an amount of alloying elements to the zinc bath. Manganese in the zinc bath can obviously restrain the growth of the coatings. The effect of manganese in the zinc bath on the coating morphology of different substrate with the different content of silicon has been investigated. The results show that the manganese in the zinc bath has little inhibiting effect to the silicon reactivity of Q345, but has visible effect on the silicon reactivity of Q235 and Fe-0.08wt.%Si. Furthermore, manganese increases the corrosion resistance and oxidation resistance of the galvanized coatings.. Manganese is one of the key alloying elements in steel, which can increase the stabi