空气净化用铜锰氧化物的研究-化学工程专业毕业论文.docxVIP

空气净化用铜锰氧化物的研究 空气净化用铜锰氧化物的研究 摘要 ^ ‘ 本论文研究铜锰氧化物催化剂，主要考察了该催化剂的室温CO氧 化性能、对Efl醛的催化氧化性能，以实现空气污染物的净化}f的。 论文采用共沉淀法制备了铜锰氧化物催化剂，深入地研究了各种制 备参数对催化剂室温CO氧化活性的影响，这些参数包括：沉淀剂种类、 滴加顺序、原料液[Cu]／[Mn]比、沉淀温度、老化pH值、老化时间、焙 烧气氛、焙烧温度、焙烧时间及焙烧气体流量，进而确定了催化剂的最 佳制备条件。制备的催化剂具有较好的活性和活性稳定性。用XRD、 SEM、TPR等技术对不同温度焙烧的催化剂进行表征，研究不同焙烧 温度下催化剂的微观结构和物相，并与催化剂活性进行关联。将该催化 剂与纳米金催化剂Au／A1203及商业化的Pd／C、Waker、Hopcalite催化 剂进行比较，考察不同催化剂的活性差异。贵金属Au、Pt、Pd的掺杂 对铜锰氧化物活性的影响不大。Ag的掺杂能够显著提高铜锰氧化物的 室温CO氧化活性及稳定性。l}kJl-，利用循环间歇反应器，测定了CO 在铜锰氧化物上的本征动力学，提出了反应动力学模型。铜锰氧化物对 甲醛的催化氧化出显示了较好的低温活性和活性稳定性。 铜锰氧化物是强氧化催化剂，在室温下对多种空气污染物具有催化 氧化效果，可作为空气净化用催化剂。 关键词：铜锰氧化物，CO氧化，甲醛，反应动力学 北京化1：人学硕Ij学位论文STUDY 北京化1：人学硕Ij学位论文 STUDY oN CoPPER．MANGANESE oXII)ES FoR AIR PURIFICATIoN 撕一 ABSTRACT 9‘ In this thesis，copper-manganese oxides catalysts were studied．The catalytic performance for the oxidation of carbon monoxide and formaldehyde at ambient temperature over copper-manganese oxides were investigated，furthermore． The copper manganese oxides were prepared using a co—precipitation procedure，in particular,the effect of a range of preparation variables were investigated in detail．The variables investigated include the precipitant、 dripping order、[Cu]／[Mn]ratio，temperature of precipitation，pH，ageing time，calcination gas，calcination temperature，calcination time and calcination gas velocity．The optimum prepatation conditions were identified with respect to the catalyst activity for the oxidation of carbon monoxide at ambient temperature．The results shown that， copper-manganese oxides had better activity and stability．A series of copper-manganese oxides catalysts calcined at different temperature were characterized by XRD、SEM and TPR techniques．The microstructure and phase were obtained and related to the catalytic activity reasonably． Compared with copper-manganese oxides and Au／A1203、commercial U 北京化T人学硕Ij学位论文Pd／C，Waker,Hopcalite 北京化T人学硕Ij学位论文 Pd／C，Waker,Hopcalite and catalytic performance of different catalysts for oxidation of carbon monoxide wer