真空低价氟化铝歧化分解制备铝.pdfVIP

1004-0609(2008)08-1550-05 1, 2 2 2 (1. 650092 2. 650093) “” 100 kPa1941.76 K100~10 Pa 1 486.32~ 1 373.28 K 300 Pa1 673 K 93.77% 1 723 K95.13% TF 131; TF 8 A Preparation of aluminum by disproportion of sub-fluoride in vacuum 1, 2 2 2 LI Qiu-xia , CHEN Wei-liang , DAI Yong-nian (1. School of Chemistry and Chemical Engineering ,Yunnan Normal University, Kunming 650092, China; 2. National Engineering Laboratory of Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China) Abstract: Thermodynamics process and experiment of aluminum extracting from bauxite and Al O , were 2 3 studied. The temperature, at which alumina, aluminum fluoride and carbon react to form aluminum sub-fluoride at different pressures, was evaluated with “Substance Gibbs’ Free Energy Functional Determinant” method. The results show that the reaction temperature can be considerable declined in vacuum, such as the temperature dropped to 1 486.32 1 373.28 K in the pressure range from 100 Pa to 10 Pa, but the temperature of the reaction needed is more than 1 941.76 K under 100 kPa. The metal aluminum with the purity of 93.77% is obtained by the experiment alumina, aluminum fluoride and carbon in a vacuum furnace when the system pressure is less than 300 Pa at 1 673 K; the aluminum metal with the purity of 95.13% is also gotten at 1 723 K by using coke for reduci