煤与瓦斯突出微观机理的基础分析-安全技术及工程专业毕业论文.docxVIP

Using Fourier transform infrared spectrometer TENSOR27, superfine pulverized coal in outburst coal and lump coal molecular structure is studied with infrared spectrum experiment. The infrared spectrum of superfine pulverized coal in outburst coal and lump coal is analyzed. Put forward the basic reasons that superfine pulverized coal in the number of groups is far less than the lump coal, lie in the organic macro-molecule side chain groups pulled off and the result of the release of low molecular compounds, thus result in producing excess gas. This experiment firstly reveals the source of the release of excess gas in coal and gas outburst process from the microscopic view. To sum up, the coal and gas adsorption, desorption and other aspects of the coal and gas outburst microscopic mechanism are put forward. In coal mine production, due to mine earthquake, mining and explosion activities, the stress change of surrounding rock on extraction face causes coal and rock mass broke, which produces electromagnetic wave with broad frequency scope. Associated molecule system formed from adsorption of coal and CH4 absorbs electromagnetic wave exceeding desorption critical frequency in form of quantum, which result in this system turns to excited state from ground state, and the gas turns to free state from adsorption state through desorption, forms a large number of free gas. If have high ground stress and condition of forming coal, therefore the dynamic phenomenon of coal and gas outburst is very easy to happen in weak plane. Keywords: coal and gas outburst; microscopic view; density functional theory; quantum mechanics; electromagnetic wave; critical frequency; adsorption; desorption; molecular structure of outburst coal. 目 录 1 绪论1 1.1 论文研究的背景和问题的提出1 1.2 国内外煤与瓦斯突出机理研究现状综述 4 1.2.1 国外研究现状综述5 1.2.2 国内研究现状综述10 1.3 煤与瓦斯吸附、脱附机理研究现状 14 1.4 存在的主要问题 20 1.5 论文研究的内容、方法及技术路线21 1.5.1 论文研究的内容21 1.5.2 论文研究的方法及技术路线22 参考文献23 2 论文研究的理论基础29 2.1 SCHR?DINGER 方程及近似 30 2.2 分子轨道理论 31 2.3 电子相关