铝酸钠溶液中有机物赋存状态的研究-分析化学专业毕业论文.docxVIP

硕士学位论文 硕士学位论文 摘要 准曲线法对铝酸钠溶液中草酸、酒石酸、乙酸、丁二酸、丁烯二酸和 戊二酸进行了定量分析。 关键词铝酸钠溶液，有机酸，气相色谱一质谱，离子色谱，高效液相 色谱 Ⅱ 硕士学位论文 硕士学位论文 ABSTRACT ABSTRACT Essential organic compounds ale identified in Bayer liquors bY GC．MS．Quantitation of organic acids in Bayer liquors by ion chromatography and reverse phase high performance liquid chromatography，respectively． Details ale as following： (1)To establish the method for identification of organic compounds in Bayer liquors by GC—MS． Separating organic compounds in Bayer liquors on HP一5 chromatography column by procedure heating using Agilent 6890 GC combineing in Agilent 5973 MS，and qualitiing the organic compounds by searching MS database．The results show that primary organic compounds in Bayer liquors ale organic acids，it is confirmed including oxalic acid，acetic acid，propionie acid，butyric acid,isobutyric acid， valeric acid，benzoic acid，succinic acid，glutaric acid，o-phthalic acid， and also including long-carbochain organic acids， for instance， tetradecoic acid，palmic acid，stearie acid．In addition，the species and content of organic compounds have great difference in Bayer liquors in different producing areas． (2)The research provided the method for simultaneous determination of organic acids and inorganic anions in Bayer liquors by IC． The samples are pretreated by cation exchange resin column and OnGuard H column respectively．The experiment adopts US Dionex Co． ICS一2500 IC apparatus by gradient ion chromatography with suppressed conductivity detection．The flow rate is 1．20ml／min，sample size is 25pL， and column temperature is 300C．By calculating concentration results from the peak area data，in 33 rain，Formate，acetate，propionate，oxalate， succinate，glutarate，D—phthalate，fluoride，chloride and sulfate were separated and determined on an IortPac AS 1 l-HC column with KOH as the eluent． III 硕士学位论文 硕