空心钡铁氧体微球的制备与性能研究-材料学专业毕业论文.docxVIP

AbstractCore．shell Abstract Core．shell composite particles consisting of of Polystyrene(PS) and shell of Ba—ferrite precursor(BFP)were prepared by way of heterogeneous nucleation，and the yielded composite particles were heat．treated．The PS，composite particles and hollow microspheres were characterized by zetaPALS Zeta potential／particles size analysis instrument， infrared spectroscopy，thermo—gravimetric analysis。differential scanning calorimeter，X．ray diffraction and transmission electron microscopy．And the static magnetic property of hollow microspheres was characterized by Vibration Sample Magnetometry． Polystyrene microspheres synthesized by soap‘free polymerization were studied．The result showed that the potential of microsphere was minus； that the dispersion and stability of microsphere was good；that the diameter of microsphere decreased with the density of initiating agent increasing when other factors were invariable． Core．shell composite particles PS／BFP were fabricated by way of heterogeneous nucleation：in the reaction system，Ba“and Fe3+were absorbed the surface of microspheres，and then the microspheres were wrapped by Drecipitation of Ba2+and Fe3+after precipitator of Ba2+and Fe3+added in the system．The potential of core—shell composite particles were still minus， multiple layers of BFP the surface of microspheres could be obtained． The core—shell composite particles PS／BFP were heat—treated．The process of heat．treatment showed that PS microspheres were decomposed about 3000C．and Ba—ferrite hollow microphere was obtained about 750”C． With heat treatment temperature increasing，the saturation magnetization increased． Keywords：heterogenous nucleation，core·shell composite particles，hollow microspheres，Ba—ferrite 武汉理r大学硕士论文第1章 武汉理r大学硕士论文 第1章 绪论 1，1引言 主要成分为Fe304的磁铁矿是人类最早接触到的铁氧体，这种铁矿 矿石古称慈石，后又称为磁石。磁石是在地磁场中被磁化而成为天然 存在的永磁体。磁石的相互吸引和磁石吸引铁是人类最初观察到的磁 现象。我国劳动人民最先发明用磁石制作方向指示器(指南针或司南)， 也是最早铁氧体的记录。那么，铁氧体究竟是一种什么样的物质呢? 现在，人们对铁氧体的定义是铁和其它一种或多种适当的金属元素组 成的复合氧化物，是一种非金属磁性材料，又称磁性瓷