铝酸锶：铕系发光材料的制备研究-材料学专业毕业论文.docxVIP

AbstractSrAl204：Eu2+，D广phosphor Abstract SrAl204：Eu2+，D广phosphor powders were prepared by solid state reaction method．The influences of raw materials and their adding ways，synthesizing temperature，the kinds and adding quantity of flux，and the ratio of A1／Sr on luminescence properties were studied．Furthermore，SrAl204：Eu2+，Dy3十was synthesized by the surface diffusion method and the influences of technological parameters on luminescence performance were discussed．Based 013．SrAl20,：Eu， (Srl．xMx)A1204：Eu(M-=Ca，Ba)were synthesized，and studied on crystal structure and luminescence performance． The results show that with soluble—salt doping way of rare earth ion， luminescence intensity Can be improved because of its uniform distribution in crystal lattice of the matrix．Additionally,AI derived from A1(OH)3 can increase the luminescence intensity,because the higher reaction activity ofAl(OH)3 makes matrix phase crystallize well． Synthesizing temperature has considemble influence on the luminescence intensity．In the range of 1200C～1350C，higher luminescence intensity Can be gained．and the optimum synthesizing temperature is 1200℃according wi廿l luminescence performance and energy consumption． NI-b,H2P04，LiF and H3803 used as flux call distinctly improve the luminescence intensity．Among the flux，the best is NH4H2P04，while AIF3 and CaF2 as flux play a little role 01decrease the luminescence intensity． Chemical composition with slight AI-Rjch Can increase luminescence intensity and prolong afte皤OW time，beeanse more Sr vacancies make rare earth ions easily and uniformly hold the Sr site in matrix to form the luminescence centers and the hole traps． Ininvestigationof(srl．xMx)A1204：Eu(M=Ca，Ba)，the results showthat Ca possesses many USeS such as making composition uniform，helping Eu delusion， stabilizing hexangular phase and improving thermal degradation．Ba has little influence on crystal structure and decreases luminescence intensity and thermal degradation．Phosphor degradation． Pho