镁铁层状双氢氧化物合成及其分散体系性能研究-化学工程专业毕业论文.docxVIP

摘 摘 要 米用液相共沉淀法合成，Mg—Fe—LDHs纳米颗粒。考祭，粒子彤貌、化学组 成、晶体结构、阴离子交换容量及原料配比的影哦发现Mg／Fe摩尔比在2：l一4：1 范围内样品具有水滑石层状六方晶系结构，有良好的结晶度，颗粒为规则的六边 形片状纳米颗粒：随Mg／Fe摩尔比从2：1增大到4：1，晶胞参数a从0．317nm减 少到0．310nm，晶胞参数c从2．380hm增大到2．412nm，层间距从0．793nm增大 到。．8。4nm，阴离子交换容量o．52m。1／g，从增大到1．28m。l屈)一：∥ 研究了Mg-Fe—LDHs分散体系的稳定性。e现随着pH值和Mg—Fe LDHs吲含 量的增加，体系悬浮性变差，AICl3、聚乙二醇、span20的加入对体系有保护作 鼠，， 研弼Mg—Fe—LDHs一钠质蒙脱土分散体系的流变学性质和触变性，讨论了lF 电颗粒与负电颗粒之间的相互作用和缔合方式。f袅现颗粒之间可能通过边一面、 边一边缔合形成絮凝块和形成三维网状结构。所研究的悬浮体的流型为牛顿型流 体和类似假塑性流体，调节Mg—Fe—I．DHs样品的加入量，可以改变体系的流型并 且在‘定条件下增大了体系的动切力：Mg Fe—LDHs钠质蒙脱土分散体系具有独 特的触变性，一定条件下体系可表现正触变性、负触变性、复合触变性，电解质 的加入对体系的流性和触变性影响有限≯7一厂一～ ， 【关键词】Mg—Fe LDHs钠质蒙脱土分散体系悬浮率 流变性触变性 AbstractThe Abstract The nanoparticles of magnesium ferric layered double hydroxides (Mg—Fe．LDHs)was synthesized by coprecipition method，and their shape chemical composition，crystal structure，anion exchange capacity and the effects of the gg／Fe ratios in raw material on these properties were studied by transmission electron microscope，chemical analysis and X ray diffraction etc．It was found that the Mg-Fe—LDHs particles are plate-like nanoparticles，and their chemical compositions are basically consistent with the composition of raw materials．In the range of Mg：Fe molar ratio in the chemical composition of the samples from 2：1 to 4：1．the particle size of the samples increases from 37．9 nm to 6 1．2 nm，and the lattice constant，a，of the hexagonal cell decreases from 0．3 1 7 nm to 0．3 1 0 nm and the lattice constant，C，of the hexagonal cell increases from 2．380 nm to 2．412 nm．and basal spacing ofthe Mg·Fe—LDHs increases from 0．793 nm to O．804 nm．the anion exchange capacity of the Mg-Fe—LDHs ncreases from 0．52 mmol／g to 1．82 mmol馆 The study on the stability of Mg·-Fe—·LDHs dispersion found that it decreases with the increase of pH and the solid content，and that AICl3 polyethaneol，span20 can protect its suspension The rheological and thixotropic behavior of Mg·-Fe-·LDHs·-MT dispersion were studied．It is found that the particles may interact by edg