氯铝酸盐离子液体合成AlH3的分析-无机化学专业毕业论文.docxVIP

哈尔滨工业大学理学硕士学位论文 哈尔滨工业大学理学硕士学位论文 - - PAGE IV - Abstract The aluminium hydride (AlH3) has a high hydrogen storage density, whose volume energy density can reach to 4.9 kWh/L, mass density can be up to 10wt%. Compared with other metal hydride (MH), The hydrogen content of AlH3 is so high that by far it has the most value of research among the metal hydride. However the study, especially the synthesis methods of AlH3 at home and abroad, is basically at a standstill. In this paper, we demonstrate a scheme using ionic liquids as reaction medium and catalyst, to synthesis AlH3, and meanwhile handle the aluminum to improve its activity, which is used as a reagent in dry method which is low-cost, together we do some experiments using dry method. The preparation of ionic liquid, we use trimethylbenzyl-ammonium chloride (TMPAC) and aluminium chloride (AlCl3) to synthesis the neutral ionic liquid under certain condition. Through the design of orthogonal experiments, the best synthetic conditions are determined, and the main and secondary factors influencing the synthesis are found. Through Fourier Infrared test, we can identify the anion and the cation in the neutral ionic liquid. Because the surrounding of existence of AlH3 is neutral or alkaline conditions, combined with the literature report, we find out the optimal synthesis of neutral ionic liquid. Determined by ultraviolet synthetic material and nuclear magnetic, further details of ionic liquids are got. The preparation of AlH3, based on the principle that is the ionic liquid can dissolve all the hydride, and preliminary exploration its dissolving principle is the ionic compounds can be dissolved under the strong electrostatic interaction generated by the anion and the cation in ionic liquid and split into two or more free mobility of ions, then in the process of post processing, make a new combination of the ions, to get products. Using the LiAlH4, LiH and AlCl3 as reagent materials, we synthetize the AlH3, and through