蒙脱土负载希夫碱配合物的制备及其催化氧化性能研究-高分子化学与物理专业毕业论文.docxVIP

硕士毕业论文摘要201 硕士毕业论文 摘要 2011 年 5 月 西北师范大学化学化工学院II 西北师范大学 化学化工学院 II Mn-DD-ol-S-MMT 的催化活性最大，并以此为例，考察了催化剂用量，反应温 度，反应时间，对其氧化性能的影响。 第五章：蒙脱土负载空间不对称希夫碱配合物的制备及其催化氧化环己烯 利用控制反应物配比的方法，合成新型含有功能基团（乙酰基）的 4,6-二乙 酰基间苯二酚缩邻苯二胺缩水杨醛，并用 FT-IR，1H-NMR，MS 对其结构进行了 表征。采用离子交换法制备了四种无机高分子负载新型希夫碱金属配合物 M-DAR-PDA-S-MMT（M=Cu2+、Co2+、Ni2+、Mn2+）。使用分子氧为氧源，催化 氧化环己烯，氧化产物为环氧环己烷（EXO），环己烯醇（-OH），环己烯酮（C=O） 和环己烯过氧化氢（-OOH）。其中催化剂 Mn-DAR-PDA-S-MMT 的活性最高， 在最佳反应条件下（温度：70℃，反应时间：10 h，催化剂用量：50 mg）环己 烯转化率可以达到 62.58%。 关键词：蒙脱土；希夫碱配合物；分子氧；环己烯 西北师范大学化学化工学院 PAGE VIII 西北师范大学 化学化工学院 PAGE VIII ABSTRACT Schiff base complexes of transition metal ions show high catalytic activity in various reactions. Much attention has been paid to its study and applications. However, those homogenous catalysts are difficult to be separated from reaction system and easy to inactive because of dimerization. The supported metal complexes also showed high catalytic activity and selectivity in comparison to unsupported complexes. The methods immobilizing mental complex involve encapsulating metal complexes into or onto inorganic supports or anchoring the complexes on organic or inorganic supports via formation of a bond between the complex and the supports. In this papers, we have attempted to use monmorillonite as the host materials for immobilization of various schiff base complexes. The reaction was performed under mild conditions using the molecular oxygen as oxidant. The dissertation includes the following contents: Chapter 1: Reviews Introduced the synthetic methods of schiff base and the host materials of supported metal complexes, make an overview of the application of in the chemical catalytic reaction (Including oxidation, epoxidation, polymerization ,ring opening polymerization and other reaction). Chapter 2: Synthesis and Catalytic Properties of Montmorillonite-immobilized New Schiff-base complexes A new Schiff base, DAR-PDA were synthesized and characterized by means of FT-IR，1H-NMR and MS. Four mental complexes (Cu, Co, Ni,Mn) were imm