棉纤维的阻燃改性及其热降解研究-高分子化学与物理专业毕业论文.docxVIP

I I II II 摘 要 摘 要 全文共分四部分 首先 对纺织品阻燃研究的必要性及现状进行了分析 阐述了本课题研究的 目的及意义 引用参考文献 46 篇 其次 用一系列无机化合物 THPC Pyrovatex CP 及其协效剂等对棉纤维进 行阻燃处理 通过热分析 红外光谱 氧指数等对其阻燃性能及热降解行为进行 分析 与纯棉纤维相比 阻燃后的纤维热降解行为发生如下变化 (a)热降解起始 温度提前 (b)热降解反应活化能降低 (c)剩炭率和氧指数提高 第三 对阻燃改性的棉纤维进行金属离子后处理 金属离子与纤维形成金属 络合物 然后采用热分析 红外光谱 剩炭率等方法对其热降解行为进行研究 结果表明 金属络合的阻燃纤维素热降解反应活化能进一步降低 剩炭率有所提 高 最后 用含磷 氮 硼等的阻燃剂对麻纤维素进行了阻燃处理 并对其热解 行为进行研究 结果表明 含磷阻燃剂催化纤维脱水成炭 含氮阻燃剂热解生成 惰性气体而起阻燃作用 含硼阻燃剂分解生成玻璃质覆盖层 隔热 隔氧 达到 阻燃目的 关键词 棉纤维素 纺织品 阻燃剂 热降解 热分析 abstract abstract 第 第 1 章 绪 论 Study on the Thermal Degradation of Cotton Cellulose Treated with Flame Retardants Abstract This thesis consists of four sections. First of all, the necessity of studying on the flame retardance of textiles was reviewed, as well as the recent studies on the thermal degradation of cotton with flame retardants was analyzed. Then the significance and purpose of this paper were also summarized. Forty-six references were cited. Secondly, cotton cellulose was treated with flame retardants such as inorganic compounds, tetrakis(hydroxymethyl)phosphonium chloride(THPC), N-methyloldimet- hylphosphonopropionamide(CP) and synergistic agents. The flame retardance and thermal degradation of the treated cotton were studied by thermal analysis, IR, and limiting oxygen index. Compared with pure cotton cellulose, the changes of thermal decomposition behavior in the treated cellulose are as follows: (a) lowering in thermal degradation onset temperature; (b) decreasing in the activation energy of decomposition process; (c) increasing in char yield and limiting oxygen index. Thirdly, coordinate complexes of cellulose treated with flame retardants were prepared by reacting with metal ions. The thermal degradation of them was studied by thermal analysis, IR, and char yield. The results show that the activation energies of them decrease further, and char yields increase a little. Finally, thermal degradation of hemp cellulose treated with various compounds containing phosphorus, n