螺噁嗪掺杂的聚合物薄膜光存储性质的研究-理论物理专业毕业论文.docxVIP

AbstractSpirooxazines(SOs)and Abstract Spirooxazines(SOs)and spiropyrans(SPs)are typical organic compounds exhibiting photochromism．Compared to SPs，SOs show better fatigue resistance and photostability and provides a possibility of practical applications in lenses of variable optical density,displays，filters and optical—memory devices．Photochromic feature of SOs and SPs arises from carbon．oxygen (Cspfro-O)bond cleavage of the colorless spiro form upon UV-light excitation and subsequent isomerization to colored open forms which are called photomerocyanines(PMCs)．PMCs carl revert to the initial spiro forms thermally or photochemically,SOs are transparent with low nonlinear optical properties，while PMCs are blue and highly nonlinear because of their non-centre symmetry and electron conjugation． Photo-induced birefringence of spirooxazine (6-piperidino-1，3，3-trimethylspiro [indolino一2，3’[3H]naphtha-[2，1-b][1，4]oxazine])(so—P)in poly(methyl methacrylate)(PMMA) fihns pre—irradiated by ultraviolet light was investigated as a function of He-Ne laser(632．8nm) pumping-beam intensity． A phenomenological model，taking photo—orientation and photo-isomerization into account，is in good agreement with the measurements．This material exhibited a competing process between photo—orienmtion and photo—isomerization．The photo—orientation is predominant when the power density of He-Ne beam is lower；while the photo—isomerization is dominant at relatively high power density of He-Ne beam．Photo—induced birefiingence of spirooxazine-doped PMMA films was alternately pumped by S and P polarized He-Ne beams(632．8urn)of 10 mW．A dynamics ofphoto—induced birefringence was recorded by a linearly polarized double—frequency Nd：YAG laser r532 nm)of 0．1 mW as a probe beam．It was found that the transmittance signal Was modulated by the polarization of the pumping beams and the maximum of the transmiRance signals in each period versus time dropped gradually to a steady value．The equilibriums of photo—ori