镁铝系储氢合金的制备及改性研究-材料科学与工程专业毕业论文.docxVIP

重庆大学 重庆大学硕士学位论文 英文摘要 PAGE PAGE IV desorption at a high hydrogen pressure of 1.5MPa. Using microwave sintering prepared Mg17Al12 alloy under different conditions, the hydrogen absorption and desorption properties of the test results showed that microwave sintering furnace power is 4kw, sintering time is 30min, the alloy can obtain the best performance, in 90min hydrogen absorption capacity reached 3.83 wt% at 350 ℃, the hydrogen desorption rate was 76.50%. Mg17Al12 +5% Ni alloy and Mg17Al12 +10% Ni alloy prepared by microwave sintering process analyzed by XRD and p-C-T test devices. Though the results, Hydrogen absorption and desorption properties of the alloy decreased compared with the alloy prepared by mechanical alloying components. As Ni can absorb microwave, increasing the effective absorbing amount of the sample, thus caused excessive sintering phenomenon, and resulting in decreased performance of the alloy. Keywords: Mg-Al-based hydrogen storage alloys, Mechanical alloying, Microwave sintering Composite modified 重庆大学硕 重庆大学硕士学位论文 目 录 目 录 中文摘要········································································································ I 英文摘要······································································································· II 1 绪论 1 1.1 氢能系统的开发目的和意义 ···········································································1 1.2 储氢材料的原理 ··························································································2 1.2.1 储氢材料简介 ·······················································································2 1.2.2 吸氢反应机理 ························································································3 1.2.3 储氢材料的热力学特性[9] ·········································································4 1.3 Mg-Al 系储氢合金的进展 6 1.4 储氢材料的制备方法 ··················································