空气中碘的形态研究-理学;环境科学专业毕业论文.docxVIP

唰叩M 唰叩MOO 阳肌川 ，， mwmadw 川川川hg 州州A唔 mm川00 唰唰m川 a-- 州州Y 摘要 摘要 本实验通过大气分级采样器采集空气中各种形态的腆，采用高温热水解翩催 化分光光度法测定。为了采集空气中各种形态的腆，专门设计…套可以收集各 种形态的腆的大气来样装置。让空气依次通过各种滤膜，以收集颗粒态腆(普 通玻璃纤维滤膜)、 HI 和 h (浸琐NAOH 的玻璃纤维滤膜)、 HOI (浸溃四丁基 氮氧化钱的玻璃纤维滤膜)、有机结合态腆(铺有活性炭的破璃纤维滤膜)。采 集样品后，用高祖热水解 J申饰催化分光光度法，测定其中的腆含量。同时采集 了一批马尾松样品，测定马尾松各组织器官中的腆含量。 本文测定和分析了浙江、山东、江西、贵阳等地区空气中各种腆形态的百 分含量，同时测定分析了这些地区马路松各组织器官中的腆含量。得出在 0-80KM 范围内，随着距离海洋的距离的增加，空气中有机结合态腆的百分含最 逐渐降低，颗粒态腆的含量逐渐升高， HI、b、HOI 的百分含量也呈现升高的趋 势。在距海 500KM 以上班围的内陆地区空气中 HI、b、HOI 形态的帧很少。在 石灰岩地区，空气中颗粒态腆百分含量显著地高于花岗岩地区，有机结合态腆 百分含最显著地低于花岗岩地区。通过分析马尾松各组织器官中的腆含最发现， 松皮〉者叶〉嫩叶〉松枝。 关键词:空气中各种形态的腆:马尾松:高温热水解肺饰催化分光光度法 1 ABSTRACT ABSTRACT The topic of the research is the collection of various iodine species in atmosphere by speciation air sampler，and 也 iodine detennination using hydrolysis咽创ytic spectrophotometry. A specia1ized iodine species sampling outfit in1aying untreated glass fiber filter，NaOH-impregnated glass fiber filter，tetrabutyl ammonium hydroxide-impre 伊ated glass fiber filter and activated carbon-impregnated glass fiber filter sequently designed to collect various iodine species in atmosphere. Particulate iodine，HI and h，HOI，organic-bound iodine were collected in order of filters wi伽 the circulating of air 由rough sampler. Hydrolysis-arsenic and cerium ca阳i严ic spec仕ophotometry method were employed to determine the content of four iodine species. In addition a batch of Masson Pine wωsampled; the iodine contents in the organs ofMasson Pine were also measured. In the research，the percen阳ge content of various iodine species in atmosphere and the content of iodine in the organs of Masson Pine from Zhejiang，Jiangxi， Shandong，Guizhou provinces were determined. Within the dis阳nce of 0-80 km from the coastline，the percentage content of organic-bound iodine in atmosphere declines gradually with the increase of distance from 由e sea; but the variation of particulate iodine displays opposite rule compared wi也 org