煤炭直接液化体系高温高压气液相平衡研究-化学工艺专业毕业论文.docxVIP

煤炭科学研究总院硕士学位论文 煤炭科学研究总院硕士学位论文 11 11 abstract ηle system involved in direct coal liquefaction is a three-phase s阳te of solid， liquid， and gωphases under high temperature and high pressure. The substance of liquid phase is composed of a number of the hydrocarbons.ηle compositions and states of the reactants and produc也 influence the process of direct coal liquefaction and the data of gas-liquid phase equilibrium at high pressures provides fundamental information for the development of direct coal li明白ction processing as well as 由e design of reaction plant. The second task of the fundamental research project on largescale direct coal liquefaction ，issued in the 973 program Basic research on large scale direct coalliquefaction in 2004，is to study the thermodynamic properties of the liquefaction products. One of the challenges in the analysis of the Coal hydrogenating process is due ωthe fact that the contents of b创b hydrogen and methane are very high and both of them are in the super.ωcritical s阳te. Besides，when small，spherical hydrogen and methane molecules are mixed with liquefaction oil，the huge difference between their molecule weights causes ex饷meωymmetry of the system，bring about the difficulty in analysis and modeling of the liquefaction process. 币lis thesis focuses on the development of the mathematical model for the process of coal 1叩efaction by predicting 伽 thermodynamic properties of the liquefaction products based on 由e fundamental variables including tempera阳阳， pressure，and compos性ion.ηle 位aditional constitutive relations of mixed rules can not precisely describe the behaviors of liquid phase，particul町ly in 也e polar system or extremely as归nmetric system. However，with the new EOS- GE Gibbs 仕ee energy model，reasonable results are able to be obtained in the s廿ong polar and strong m严nme甘ical system of coal liquefaction under high temperature and high pressure， by combining the model of activity coe何icients and constitutive relatio