锂二次电池用碳基复合纳米电极材料制备与性能研究-化学工艺专业毕业论文.docxVIP

锂二次电池用碳基复合纳米电极材料制备与性能研究电极及放电产物Li202质量为基准计算的能量密度高达1870．2570 锂二次电池用碳基复合纳米电极材料制备与性能研究 电极及放电产物Li202质量为基准计算的能量密度高达1870．2570 Wh kg一，远超目前锂 离子电池正极LiC002的性能。 关键词：碳材料；复合纳米材料；电极材料；锂离子电池；锂空气电池： 万方数据 大连理工大学博士学位论文ABSTRACT 大连理工大学博士学位论文 ABSTRACT The electrochemical performance of current lithium secondary baReries IS too low to meet the rapid developed energy—intensive technologies such as the electrical vehicles． Therefore，it is highly desirable to develop novel electrode materials with much higher energy density．The construction of high—energy lithium secondary battery strongly depends on the regulation of the composition，structure and functional characteristics of electrochemically active materials to improve the structure thermodynamic stability and reaction kinetics．In this study，we focus on the design and synthesis of carbon-based nanohybrids as high performance electrode materials for lithium secondary batteries by improving or optimizing their surface characteristics，morphology，and porous structure to achieving high capacity and superior lifespan．The detailed study includes： Polycyanamide coupled graphene hybrids have been developed by in—situ polymerization of the cyanamide on graphene nanosheets，which greatly inherits the conductivity and stability of graphene nanosheets．The presence of polycyanamide layer with extremely high nitrogen content modifies the interfacial properties and facilitates the strong coupling of ultrafine Fe304 nanoparticles on the surface，which leads to the formation of nitrogen-rich carbon coupled Fe30nJgraphene nanohybrids．The nanostructure decreases the transport path of Li+and electrons and enhances the integral structure and interfacial stability．As a result． the nanohybrids exhibit excellent durability for long—term cycling and superior rate response， as characterized by high capacity retention of over 80％for as long as 1 000 cycles at high current densities of 2—5 A g～．Remarkably．comparable capacities of 443 mA h g。1 Can still remain at a hig