锂离子电池正极材料磷酸锰锂的制备与改性-能源化工专业毕业论文.docxVIP

Preparation Preparation and modification of LiMnP04 for high performance lithium·ion battery cathode Abstract The capacity bottleneck of lithium—ion battery，as a new type of chemical power source． is still the capacity upper limit of the positive materials．It is worth mentioning that the LiMnP04 has been a hot research topic in the positive materials，which is cheaper，safer and more stable，and has 20％higher redox potential than that of LiFeP04．Therefore，it is considered as the cathode for a new generation of power battery,and thus has great development potential．However，it is restricted by the sluggish kinetics of electron and lithium ion migration in crystal lattice．As a general rule，major obstacles Can be overcome by controlling nanoparticle granularity，applying electrically conductive coatings and ion—doping． In this thesis，we have developed a systematic study method to synthesize nanosized L．iMnP04／C and a universal method to study ion—doping，described as the following two parts： (1)An improved approach has been proposed for the synthesis of nanosized LiMnP04 with more active a-c planes，a regular micromorphology and conductive carbon layer by using a two—step microwave solvothermal process．A systematic study has been conducted to find the optimum operation conditions．The sample synthesized at 1 60。C for 1 0 min gives the best performance and shows excellent cyclic stability with a capacity of 1 55 mA h g。1 at 0．5 C after l 00 cycles and surprising rate performance of 1 1 8 mA h g～at 1 0 C．The best sample (LMP／NC)shows an excellent low temperature performance retaining 80％of its theoretical capacity at 2。C．These excellent results are ascribled to a specific crystal orientation and the high conductivity and nano—confinement of carbon coating that contains a small amount of nitrogen．The overall process has short synthesis times and scale—up potential． (2)An impregnation method has been developed to investigate the influence of ion·doping in LiMnP04 on its ch