离子热合成磷酸铝分子筛的研究-化学工程专业毕业论文.docxVIP

研究生优秀毕业论文 摘要摘要 摘要 摘要 分子筛是一种具有规则的孔道结构和离子交换性能的材料，广泛应用于石油化 工，煤化工，精细化工，生物分离，分子器件，光学等诸多领域。本文采用离子热 合成法在280℃下合成了磷酸铝分子筛，并研究了离子热合成磷酸铝分子筛的机理。 1．研究了不同反应条件对合成磷酸铝分子筛的影响，确定了合适的反应条件： 以[BMIM]Br为溶剂，二正丙胺为模板剂，以P／AI=-3加料，晶化时间为8min。在此 条件下合成A1P04．5分子筛具有良好的热稳定性。 2．在以上条件下对离子热合成A1P04．5和A1P04．42的晶化机理做了研究，证实 AIP04—5和A1P04—42的晶化机理符合固相转晶机理。 3．对A1P04．5磷酸铝分子筛转晶过程进行了研究，发现了从A1P04—5到A1P04．11 到方石英到MS的转晶过程。从SEM和UV Raman的结果推测A1P04．5的转晶过程 中既有固相转晶机理，又有液相转晶机理。 关键词分子筛；离子热合成；反应条件；转晶过程：晶化机理 万方数据 河北科技大学研士学位论文 II 万方数据 AbstractAbstract Abstract Abstract Molecular sieve iS a kind of material with rules of pore structure and ion exchange properties．It is widely used in petrochemical，coal chemical，fine chemical，biological separation，molecular devices，optical fields．In this work，aluminum phosphate molecular sieve are synthesized at 280。C by ionothermal synthesis．The mechanism of ionothermal synthesis of aluminum phosphate molecular sieve is studied aS well． 1．The influence of different reaction conditions for synthesis of aluminum phosphate is studied．A appropriate reaction conditions is confirmed：using[BMIM]Br as solvent， n—DPA aS template agent，P／A1=3 and the crystallization time is 8min． 2．The study of the crystallization mechanism for A1P04．5 and A1P04-42 is done under the above reaction conditions．It iS determined that the crystallization mechanism of AIP04．5 and AIP04-42 followed the solid phase transformation mechanism． 3．The crystal transition process of AIP04—5 aluminum phosphate molecular sieve is researched．A series of crystal transkion process is found from A1P04—5 to A1P04．1 1 to cristobalite to MS．Through the results of SEM and UV Raman inferred that both solid phase transformation mechanism and liquid crystal transition mechanism are existed in the crystal transition process ofAlP04-5． Keywords molecular sieve； ionothermal synthesis reaction condition； crystal transition process；crystallization mechanism I¨ 万方数据 河北科技大学硕士学位论文 IV 万方数据 目 目 录 目 录 摘 要 ·· Abstract 一 ‘ ‘‘ ’‘‘ ·-一III 第1章绪论 ．．1 1．1前言 ．1 1．