联苯癸烷结构双咪唑交联的聚砜碱性膜-精细化工专业毕业论文.docxVIP

联封癸烷结构双咪唑交联的聚砜碱性膜Polysulfone—based 联封癸烷结构双咪唑交联的聚砜碱性膜 Polysulfone—based Alkaline Membranes Crosslinked by Bis—imidazoliums with Diphenyl／Decyl Structures Abstract The hydroxide exchange membrane(HEM)is one core component of HEMFC．The hydroxide conductivity，alkaline and thermal stability，mechanical property and stability of HEM greatly influence the working state of the battery．Currently，gaining high hydroxide conductivity is the hot and difficult spot of the HEM RD．Usually，the HC enhancement is conducted directly by increasing the density of the ion exchange groups．However，the much higher density often causes excessive swelling，which leads to the losing of the dimensional stability of the HEM．Crosslinking conducted by functional group-containing crosslinker is one of the most effective methods for preparing the HEM with excellent dimensional stability． This method has these advantages，such as，achieving much higher density of ion exchange groups，wide applicability．However，currently，the HCs of these HEMs based on the functional group-containing crosslinkers are still low．Therefore，in order to obtain high HC of the crosslinking HEM，the rigid biphenyl and flexible long alkyl chain(decane)were intoduced to the crosslinking modification of HEM．The large volume of the biphenyl and decane structures can promote the micro-phase separation of the main chains，which will improve the HC of the HEM．And，the long alkyl chain can improve the alkaline stability of the HEM． In the present work，the polysulfone membranes with different degrees of chloromethylation modified by 1,2-dimethyl-imidazolium were prepared，which provided a basis for the subsequent research．The high reactivity between chloromethyl and imidazole， and the much better ion exchange property of imidazolium were demonstrated by the NMR and the measured ion exchange capacity(IEC)．In addition，the HEM with theoretical IEC of 2．1 6 mmol g。1 has a very high conductivity of 53 mS cm。1 at 20 oC which is similar to the 60 mS