离子材料协同酸催化C4烷基化反应研究-化学工程专业毕业论文.docxVIP

洞北科技大学硕士学位论文 E 万方数据 AbsWactAbstract AbsWact Abstract The alkylate produced in isobutane alkylation process as an important industr／al product in petroleum refining industry is the ideal additive to enhance the quality of gasoline The alkylate produced in the isobutane alkylation process arc important industrial products in the petroleum refining industry because of their ideal nature as gasoline additives to enhance the quality and combustion performance in the spark ignition engine． Facing with the more sevel℃environmental issues，the traditional alkylation industry technology is obsolete．So it’S urgent to improve the alkylation technology,with special emphasis on the alkylation catalysts．Based on this insight,We carded out our work to deal with this problem． In this work a series of ionic liquids containing N—cations[N_222明+which are blended with triflic acid were synthesized and investigated for their catalytic performance in triflic acid／ionic liquids synergistically catalyzed isobutane alkylation process．Through studying the acid strength of the triflic acid modified by ionic nquid[N222明CF3S03，we found that the acid strength of triflic acid／ionic liquid was stable because the presence of the anionic cluster[Nz22H(CF3S03)x]．It makes the triflic acid／ionic liquids system a potential alkylation catalyst．The result of evaluating the catalytic performance of 【N222网CFsS03／CFsS03Hsystemcatalyzedalkylationshowsthatthehigh-qualityalkylate of RON up to 97．3，C8 selectivity up to 86．23％was got．The result of reusability of the 斟222明CF3S03／CF3S03H and pure CF3S03H shows that the service life of catalyst system [N222明CF3S03／CF3S03H is about 1．7 times of that of pure CF3S03H，and the RON of alkylate obtained by叫五H】CF3SOffCF3S03H is higher than that ofpure CF3S03H by 3． Apart from the above work,the acidic polymeric ionic liquids catalyst、^，itll the advantages of polymer and ionic liquids was prepared，and the process to prepare acidic polymeric ionic liquid was studied．The surfac