磷氰酸根负离子对构建新型含磷化合物的研究-有机化学专业毕业论文.docxVIP

DEDICATl0NDedicated DEDICATl0N Dedicated to my parents and sister For their endless love and all aspects of support Dedicated to my girlfriend Sunny For her endless love and understanding 万方数据 致谢would 致谢 would like to thank all Zhao and Bertrand group members，both past and present，for helpful chemistry(and geneml)discussions and for making the lab a very enjoyable place towork． To my advisor,Prof．Yufen Zhao，thank you so much for providing me the opportunity to be a member of your group in Xiamen University(XMU)．Thanks for giving me the chance to gO to Califomia to study for 2 years and taking me to atIend an international conference (ICPC2012)in the Netherland and several meetings in China．I have definitely grown a lot over the course of the past years．I truly appreciate the times when 1 would discuss with you．sometimes for several hours，allowing me to see how phosphorus chemistry plays a crucial role in our daily life． T0 my advisor,Prof．Guy Bertrand，thank you so much for providing me the opportunity to be a member of your group in University of Califomia。San Diego(UCSD)．It has been a privilege to have an advisor who gave me the freedom to pursue what l was interested in。 and also gave advice and discussed the results，no matter how crazy they became．1 tmly appreciate the time you put in me。making me become the chemist I am today．I remember clearly that day when I came to your office showing the crude P NMR spectrum of our phosphinidene，which you mentioned“masterpiece of my PhD”．Thanks are also due to your kind help，giving me an amazing chance to further my research in the group of Prof．Douglas Stephan in University of Toronto，Canada． am also grateful to Prof．Jun Zhu at Xiamen University．who provided me the opportunity to learn computational chemistry．Almost all of my publications involve in density functional theory calculations，which could help me to understand how chemical reactions proceed and what the bonding situation of a molecule is． NMR spectroscopy be