类钙钛矿型复合氧化物催化消除N2O的研究-环境科学专业毕业论文.docx

? ? 肿Y 肿Y “Wii●■I Ⅲ9 Ⅲ4Ⅲ0 9 Ⅲ7 嗍4 黑龙江大学硕士学位论文 Abstract Nitrous oxide(N20)is now recognized as a11 environmental pollutant．It is not only a substantial contributor to catalytic ozone depletion by being a major source ofNOx in the stratosphere，but is also a greenhouse gas．N20 has 3 1 0 and 21 times the global warming potential(GWP)of C02 and CH4，respectively．To control the emission of N20 from chemical processes，the catalysts for N20 decomposition have been widely studied in the last three decades． The S01．Gel method and citrate combustion method were adopted to synthesize Perovskite or perovskite—like oxides samples in this dissertation，respectively．The structure properties of samples were characterized by XRD，and H2-TP心02-TPD were in flavor of understanding the crystal structure，surface characteristics and surface active species．The catalytic activity of several perovskite and perovskite—like catalysts were tested．and the effect ofthe alkaline earth metal ions、alkaline earth carbonate、alkaline earth oxides doped perovskite—like catalysts for catalytic decomposition of N20 were inspected．It was found that the activity in N20 direct decomposition could be improved ◆ by substituting all alkaline—earth metals for La，in which the samples of substituting Ba for La performed best activity．Doping alkaline earth oxides also had a great influence to the catalytic activity of perovskite—like．CaO can promoted the catalytic performance of perovskite．1ike in N20 direct decomposition．But BaO had serious activity inhibition． LaL6Sro．4Cu04-20％MgO samples showed excellent catalytic activities for the decomposition of N20，which Can convert 1 00％N20 to N2 at 450 degree centigrade In ● addition,the paper also researched the catalytic activity of perovskite—like mixed、析nl the alkaline earth carbonate．It Was found that the catalytic activity of perovskite—like mixed谢也20％BaC03 may be raised．The mixture of SrC03 or CaC03 was not significantly affected on the catalytic activity． Keywo