流化床粉煤灰合成沸石及处理含酚废水的研究-环境工程专业论文.docxVIP

太原理工大学硕士研究生学位论文STUDY 太原理工大学硕士研究生学位论文 STUDY 0N SYNTHESIS OF ZEOLITES W1TH CIRCULATING FLUIDIZED—BED(CFB)FLY ASH AND TREATMENT OF PHENOL WA STE、7＼啪R ABSTRACT Fly ash is a kind of granule material by combustion，which mostly comes from the coal—fire power plant．Because of cumulation for long time，fly ash occupies large space and pollutes the environment on which people living． Owing to being discharged at random，human health has been greatly harmed by fly ash． At present，the utilizing of fly ash focuses on the fields of construction and agriculture．The technological level and the economical benefit is poor． This paper studied on synthesis of zeolite with circulating fluidized—bed fly ash through the traditional hydrothermal method，exploring for the feasibility and superiority of CFB fly ash．The CFB fly ash is an active material of zeolite synthesis，including little crysal phase．So that we have no use for pretreating it by baking at a high temperature． The effects of different conditions of composition of raw materials， crystallizing time，NaOH concentration，temperature，crystallization and shape of synthetic zeolites have been investigated for the traditional hydrothermal condition．NaOH concentration has a great impact on the crystal grade of synthetic zeolite via XRD diffraction technique characterization．The relative crystallization of X zeolite is up to 60％，when the NaOH concentration is 3．00mol／L and the crystallizing time is 1 4h．As time passed，the relative crystallization will be improved．But the mixed zeolites will be produced at the same time．And when the NaOH concentration iS 3．30mol／L．P zeolite will be produced．When Si02／A1203 is 3．7，the type ofzeolite will be transformed into P I I I 太原理1：人学硕士研究生学位论文 太原理1：人学硕士研究生学位论文 zeolite． In addition，the paper studi ed the adsorption effect of the synthetic zeolites on treating with the phenol wastewater and summarized the rule of environment influen